0000000001303534

AUTHOR

Patricio Hermosilla-ibáñez

showing 11 related works from this author

Functionalization using biocompatible carboxylated cyclodextrins of iron-based nanoMIL-100

2021

9 pags., 7 figs., 1 tab.

Auger electron spectroscopyCyclodextrinsCyclodextrin applicationsNanoparticleMetal-organic frameworksInorganic ChemistryThermogravimetrychemistry.chemical_compoundMonomerchemistryPolymer chemistrypolycyclic compoundsMaterials ChemistrySurface modified nanoparticlesMössbauerSurface modificationCarboxylatePhysical and Theoretical ChemistryPorosityLinkerMaterials
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A systematic study of the optical properties of mononuclear hybrid organo-inorganic lanthanoid complexes

2020

A series of hybrid organo-inorganic mononuclear lanthanoid complexes, [n-NBu4]3[LnH(PW11O39)(phen)2]·H2O, denoted as LM4-1-Ln (Ln = DyIII, TbIII, EuIII, NdIII, ErIII, HoIII and GdIII), were synthesized via hydrothermal synthesis and were structurally characterized by X-ray diffraction. The optical properties of all complexes have been investigated in the solid state. The temperature-dependent emission spectra of LM4-1-Dy, LM4-1-Tb and LM4-1-Eu complexes show intense lanthanoid emissions in the visible region, while LM4-1-Nd shows near-infrared (NIR) luminescence. The EuIII complex shows typical strong red emissions from the 5D0 → 7F0,1,2,3,4 transitions, with the CIE colour coordinates (0.6…

Inorganic ChemistryDiffractionLanthanidePhotoluminescenceMaterials scienceTemperature sensitivityHydrothermal synthesisPhysical chemistryQuantum yieldEmission spectrumQuímicaLuminescence
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Slow Relaxation of the Magnetization on Frustrated Triangular FeIII Units with S= 1/2 Ground State: The Effect of the Highly Ordered Crystal Lattice …

2021

In order to understand how the different arrangements of highly ordered triangular FeIII S = 1/2 systems with various types of diamagnetic and paramagnetic anions affect their static and dynamic magnetic properties, we have obtained by solvothermal synthesis four new μ3-oxido trinuclear FeIII compounds, [Fe3O(Ac)6(AcNH2)3][BF4]·(CH3CONH2)0.5(H2O)0.5 (1-BF4), [Fe3O(Ac)6(AcNH2)3][GaCl4] (1-GaCl4), [Fe3O(Ac)6(AcNH2)3][FeCl4] (1-FeCl4) and [Fe3O(Ac)6(AcNH2)3][FeBr4] (1-FeBr4), where, Ac- = CH3COO- and AcNH2 = CH3CONH2. The organization of the triangular units is very varied, from segregated stacks to eclipsed equilateral triangular [Fe3O]+ units along the c-axis with intercalated [MX4]- units. …

MagnetizationMaterials scienceCondensed matter physicsRelaxation (physics)General Materials ScienceGeneral ChemistryCrystal structureCristallsQuímicaCondensed Matter PhysicsGround state
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Hybrid organic-inorganic mononuclear lanthanoid single ion magnets

2019

The first family of hybrid mononuclear organic-inorganic lanthanoid complexes is reported, based on [PW11O39]7− and 1,10-phenanthroline ligands. This hybrid approach causes a dramatic improvement of the relaxation time (×1000) with a decrease of the optimal field while maintaining the Ueff of the inorganic analogues.

LanthanideMaterials scienceSingle ionField (physics)010405 organic chemistryMetals and AlloysGeneral ChemistryQuímica010402 general chemistryHybrid approach01 natural sciencesCatalysis0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsMagnetOrganic inorganicMaterials ChemistryCeramics and CompositesPhysical chemistryMaterials
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CCDC 1951515: Experimental Crystal Structure Determination

2019

Related Article: Walter Cañón-Mancisidor, Matias Zapata-Lizama, Patricio Hermosilla-Ibáñez, Carlos Cruz, Diego Venegas-Yazigi, Guillermo Mínguez Espallargas|2019|Chem.Commun.|55|14992|doi:10.1039/C9CC07868A

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstris(tetra-n-butylammonium) (mu-phosphato)-(mu-hydroxo)-tricosakis(mu-oxido)-bis(110-phenanthroline)-undecakis(oxido)-undeca-tungsten(vi)-dysprosium(iii) monohydrateExperimental 3D Coordinates
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CCDC 1951516: Experimental Crystal Structure Determination

2019

Related Article: Walter Cañón-Mancisidor, Matias Zapata-Lizama, Patricio Hermosilla-Ibáñez, Carlos Cruz, Diego Venegas-Yazigi, Guillermo Mínguez Espallargas|2019|Chem.Commun.|55|14992|doi:10.1039/C9CC07868A

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstris(tetra-n-butylammonium) (mu-phosphato)-(mu-hydroxo)-tricosakis(mu-oxido)-bis(110-phenanthroline)-undecakis(oxido)-undeca-tungsten(vi)-erbium(iii) monohydrateExperimental 3D Coordinates
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CCDC 1951518: Experimental Crystal Structure Determination

2020

Related Article: Matias Zapata-Lizama, Patricio Hermosilla-Ibáñez, Diego Venegas-Yazigi, Guillermo Mínguez Espallargas, Lauro June Queiroz Maia, Gisane Gasparotto, Ricardo Costa De Santana, Walter Cañón-Mancisidor|2020|Inorg.Chem.Front.|7|3049|doi:10.1039/D0QI00232A

Space GroupCrystallographytris(tetra-n-butylammonium) (mu-hydroxo)-tricosakis(mu-oxo)-(mu-phosphato)-undecaoxo-bis(110-phenanthroline)-holmium-undeca-tungsten monohydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1962564: Experimental Crystal Structure Determination

2020

Related Article: Matias Zapata-Lizama, Patricio Hermosilla-Ibáñez, Diego Venegas-Yazigi, Guillermo Mínguez Espallargas, Lauro June Queiroz Maia, Gisane Gasparotto, Ricardo Costa De Santana, Walter Cañón-Mancisidor|2020|Inorg.Chem.Front.|7|3049|doi:10.1039/D0QI00232A

Space GroupCrystallographytris(tetra-n-butylammonium) (mu-hydroxo)-tricosakis(mu-oxo)-(mu-phosphato)-undecaoxo-bis(110-phenanthroline)-europium-undeca-tungsten monohydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1951517: Experimental Crystal Structure Determination

2020

Related Article: Matias Zapata-Lizama, Patricio Hermosilla-Ibáñez, Diego Venegas-Yazigi, Guillermo Mínguez Espallargas, Lauro June Queiroz Maia, Gisane Gasparotto, Ricardo Costa De Santana, Walter Cañón-Mancisidor|2020|Inorg.Chem.Front.|7|3049|doi:10.1039/D0QI00232A

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstris(tetra-n-butylammonium) (mu-hydroxo)-tricosakis(mu-oxo)-(mu-phosphato)-undecaoxo-bis(110-phenanthroline)-terbium-undeca-tungsten monohydrateExperimental 3D Coordinates
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CCDC 1962563: Experimental Crystal Structure Determination

2020

Related Article: Matias Zapata-Lizama, Patricio Hermosilla-Ibáñez, Diego Venegas-Yazigi, Guillermo Mínguez Espallargas, Lauro June Queiroz Maia, Gisane Gasparotto, Ricardo Costa De Santana, Walter Cañón-Mancisidor|2020|Inorg.Chem.Front.|7|3049|doi:10.1039/D0QI00232A

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstris(tetra-n-butylammonium) (mu-hydroxo)-tricosakis(mu-oxo)-(mu-phosphato)-undecaoxo-bis(110-phenanthroline)-neodymium-undeca-tungsten monohydrateExperimental 3D Coordinates
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CCDC 1951519: Experimental Crystal Structure Determination

2019

Related Article: Walter Cañón-Mancisidor, Matias Zapata-Lizama, Patricio Hermosilla-Ibáñez, Carlos Cruz, Diego Venegas-Yazigi, Guillermo Mínguez Espallargas|2019|Chem.Commun.|55|14992|doi:10.1039/C9CC07868A

tris(tetra-n-butylammonium) (mu-phosphato)-(mu-hydroxo)-tricosakis(mu-oxido)-bis(110-phenanthroline)-undecakis(oxido)-undeca-tungsten(vi)-gadolinium(iii) monohydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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