0000000001303534
AUTHOR
Patricio Hermosilla-ibáñez
Functionalization using biocompatible carboxylated cyclodextrins of iron-based nanoMIL-100
9 pags., 7 figs., 1 tab.
A systematic study of the optical properties of mononuclear hybrid organo-inorganic lanthanoid complexes
A series of hybrid organo-inorganic mononuclear lanthanoid complexes, [n-NBu4]3[LnH(PW11O39)(phen)2]·H2O, denoted as LM4-1-Ln (Ln = DyIII, TbIII, EuIII, NdIII, ErIII, HoIII and GdIII), were synthesized via hydrothermal synthesis and were structurally characterized by X-ray diffraction. The optical properties of all complexes have been investigated in the solid state. The temperature-dependent emission spectra of LM4-1-Dy, LM4-1-Tb and LM4-1-Eu complexes show intense lanthanoid emissions in the visible region, while LM4-1-Nd shows near-infrared (NIR) luminescence. The EuIII complex shows typical strong red emissions from the 5D0 → 7F0,1,2,3,4 transitions, with the CIE colour coordinates (0.6…
Slow Relaxation of the Magnetization on Frustrated Triangular FeIII Units with S= 1/2 Ground State: The Effect of the Highly Ordered Crystal Lattice and the Counteranions
In order to understand how the different arrangements of highly ordered triangular FeIII S = 1/2 systems with various types of diamagnetic and paramagnetic anions affect their static and dynamic magnetic properties, we have obtained by solvothermal synthesis four new μ3-oxido trinuclear FeIII compounds, [Fe3O(Ac)6(AcNH2)3][BF4]·(CH3CONH2)0.5(H2O)0.5 (1-BF4), [Fe3O(Ac)6(AcNH2)3][GaCl4] (1-GaCl4), [Fe3O(Ac)6(AcNH2)3][FeCl4] (1-FeCl4) and [Fe3O(Ac)6(AcNH2)3][FeBr4] (1-FeBr4), where, Ac- = CH3COO- and AcNH2 = CH3CONH2. The organization of the triangular units is very varied, from segregated stacks to eclipsed equilateral triangular [Fe3O]+ units along the c-axis with intercalated [MX4]- units. …
Hybrid organic-inorganic mononuclear lanthanoid single ion magnets
The first family of hybrid mononuclear organic-inorganic lanthanoid complexes is reported, based on [PW11O39]7− and 1,10-phenanthroline ligands. This hybrid approach causes a dramatic improvement of the relaxation time (×1000) with a decrease of the optimal field while maintaining the Ueff of the inorganic analogues.
CCDC 1951515: Experimental Crystal Structure Determination
Related Article: Walter Cañón-Mancisidor, Matias Zapata-Lizama, Patricio Hermosilla-Ibáñez, Carlos Cruz, Diego Venegas-Yazigi, Guillermo Mínguez Espallargas|2019|Chem.Commun.|55|14992|doi:10.1039/C9CC07868A
CCDC 1951516: Experimental Crystal Structure Determination
Related Article: Walter Cañón-Mancisidor, Matias Zapata-Lizama, Patricio Hermosilla-Ibáñez, Carlos Cruz, Diego Venegas-Yazigi, Guillermo Mínguez Espallargas|2019|Chem.Commun.|55|14992|doi:10.1039/C9CC07868A
CCDC 1951518: Experimental Crystal Structure Determination
Related Article: Matias Zapata-Lizama, Patricio Hermosilla-Ibáñez, Diego Venegas-Yazigi, Guillermo Mínguez Espallargas, Lauro June Queiroz Maia, Gisane Gasparotto, Ricardo Costa De Santana, Walter Cañón-Mancisidor|2020|Inorg.Chem.Front.|7|3049|doi:10.1039/D0QI00232A
CCDC 1962564: Experimental Crystal Structure Determination
Related Article: Matias Zapata-Lizama, Patricio Hermosilla-Ibáñez, Diego Venegas-Yazigi, Guillermo Mínguez Espallargas, Lauro June Queiroz Maia, Gisane Gasparotto, Ricardo Costa De Santana, Walter Cañón-Mancisidor|2020|Inorg.Chem.Front.|7|3049|doi:10.1039/D0QI00232A
CCDC 1951517: Experimental Crystal Structure Determination
Related Article: Matias Zapata-Lizama, Patricio Hermosilla-Ibáñez, Diego Venegas-Yazigi, Guillermo Mínguez Espallargas, Lauro June Queiroz Maia, Gisane Gasparotto, Ricardo Costa De Santana, Walter Cañón-Mancisidor|2020|Inorg.Chem.Front.|7|3049|doi:10.1039/D0QI00232A
CCDC 1962563: Experimental Crystal Structure Determination
Related Article: Matias Zapata-Lizama, Patricio Hermosilla-Ibáñez, Diego Venegas-Yazigi, Guillermo Mínguez Espallargas, Lauro June Queiroz Maia, Gisane Gasparotto, Ricardo Costa De Santana, Walter Cañón-Mancisidor|2020|Inorg.Chem.Front.|7|3049|doi:10.1039/D0QI00232A
CCDC 1951519: Experimental Crystal Structure Determination
Related Article: Walter Cañón-Mancisidor, Matias Zapata-Lizama, Patricio Hermosilla-Ibáñez, Carlos Cruz, Diego Venegas-Yazigi, Guillermo Mínguez Espallargas|2019|Chem.Commun.|55|14992|doi:10.1039/C9CC07868A