0000000001304355

AUTHOR

Marcel Dommaschk

Coordination-Induced Spin-State Switching with Nickel Chlorin and Nickel Isobacteriochlorin

We present the first coordination-induced spin-state switching with nickel chlorin and nickel isobacteriochlorin. The spin-state switching was monitored by UV-vis spectroscopy and NMR titration experiments. The association constants (K1 and K2) and thermodynamic parameters (ΔH and ΔS) of the coordination of pyridine were determined. The first X-ray analyses of a paramagnetic nickel chlorin and a nickel isobacteriochlorin provide further information about the structure of the octahedral complexes. Nickel chlorin and even more pronounced nickel isobacteriochlorin exhibit stronger coordination of axial ligands compared to the corresponding nickel porphyrin and thus provide the basis for more e…

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CCDC 1415585: Experimental Crystal Structure Determination

Related Article: Marcel Dommaschk, Vanessa Thoms, Christian Schütt, Christian Näther, Rakesh Puttreddy, Kari Rissanen, and Rainer Herges|2015|Inorg.Chem.|54|9390|doi:10.1021/acs.inorgchem.5b01756

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CCDC 1415586: Experimental Crystal Structure Determination

Related Article: Marcel Dommaschk, Vanessa Thoms, Christian Schütt, Christian Näther, Rakesh Puttreddy, Kari Rissanen, and Rainer Herges|2015|Inorg.Chem.|54|9390|doi:10.1021/acs.inorgchem.5b01756

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CCDC 1415587: Experimental Crystal Structure Determination

Related Article: Marcel Dommaschk, Vanessa Thoms, Christian Schütt, Christian Näther, Rakesh Puttreddy, Kari Rissanen, and Rainer Herges|2015|Inorg.Chem.|54|9390|doi:10.1021/acs.inorgchem.5b01756

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CCDC 1407134: Experimental Crystal Structure Determination

Related Article: Marcel Dommaschk, Vanessa Thoms, Christian Schütt, Christian Näther, Rakesh Puttreddy, Kari Rissanen, and Rainer Herges|2015|Inorg.Chem.|54|9390|doi:10.1021/acs.inorgchem.5b01756

research product

CCDC 1415588: Experimental Crystal Structure Determination

Related Article: Marcel Dommaschk, Vanessa Thoms, Christian Schütt, Christian Näther, Rakesh Puttreddy, Kari Rissanen, and Rainer Herges|2015|Inorg.Chem.|54|9390|doi:10.1021/acs.inorgchem.5b01756

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