0000000001304554
AUTHOR
Santiago Herrero
Formation of a novel ferromagnetic end-to-end cyanate bridged homochiral helical copper(ii) Schiff base complex via spontaneous symmetry breaking
A homochiral helical coordination polymer of copper(II) has been synthesized using achiral precursors via spontaneous symmetry breaking and has been confirmed by single crystal X-ray diffraction and solid-state CD spectroscopy. The variable temperature magnetic measurements indicate the presence of weak ferromagnetic exchange interactions mediated by end-to-end cyanate bridges (J = +0.12 cm(-1)).
CCDC 1019456: Experimental Crystal Structure Determination
Related Article: Anik Bhattacharyya, Biswa Nath Ghosh, Santiago Herrero, Kari Rissanen, Reyes Jiménez-Aparicio, Shouvik Chattopadhyay|2015|Dalton Trans.|44|493|doi:10.1039/C4DT03166K
CCDC 1406302: Experimental Crystal Structure Determination
Related Article: Subrata Jana, Anik Bhattacharyya, Biswa Nath Ghosh, Kari Rissanen, Santiago Herrero, Reyes Jiménez-Aparicio, Shouvik Chattopadhyay|2016|Inorg.Chim.Acta|453|715|doi:10.1016/j.ica.2016.09.005
CCDC 1406301: Experimental Crystal Structure Determination
Related Article: Subrata Jana, Anik Bhattacharyya, Biswa Nath Ghosh, Kari Rissanen, Santiago Herrero, Reyes Jiménez-Aparicio, Shouvik Chattopadhyay|2016|Inorg.Chim.Acta|453|715|doi:10.1016/j.ica.2016.09.005