6533b82ffe1ef96bd1295db3
RESEARCH PRODUCT
Formation of a novel ferromagnetic end-to-end cyanate bridged homochiral helical copper(ii) Schiff base complex via spontaneous symmetry breaking
Santiago HerreroShouvik ChattopadhyayReyes Jiménez-aparicioKari RissanenBiswa Nath GhoshAnik Bhattacharyyasubject
Circular dichroismSchiff baseStereochemistryChemistryCoordination polymerSpontaneous symmetry breakingchemistry.chemical_elementcircular dichroism spectroscopyCyanateferromagnetismsingle crystalsCopperX-ray diffractionInorganic ChemistryCrystallographychemistry.chemical_compoundfunctional groupsFerromagnetismcopperferromagnetic materialsta116Single crystaldescription
A homochiral helical coordination polymer of copper(II) has been synthesized using achiral precursors via spontaneous symmetry breaking and has been confirmed by single crystal X-ray diffraction and solid-state CD spectroscopy. The variable temperature magnetic measurements indicate the presence of weak ferromagnetic exchange interactions mediated by end-to-end cyanate bridges (J = +0.12 cm(-1)).
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2014-11-28 | Dalton Transactions |