0000000001304719

AUTHOR

Elena Oleshkevich

showing 11 related works from this author

Back Cover: Carboranylphosphinic Acids: A New Class of Purely Inorganic Ligands (Chem. Eur. J. 11/2016)

2016

Hydrogen bondComputational chemistryChemistryOrganic ChemistryCover (algebra)General ChemistryCatalysisChemistry - A European Journal
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Carboranylphosphinic Acids: A New Class of Purely Inorganic Ligands

2015

Purely inorganic carboranyl phosphinates were prepared, and the influence of the cluster on the reactivity of the phosphinate group was studied. Electron-withdrawal by the carboranyl carbon atoms, combined with space-filling efficiency and enhanced aromaticity of the cluster cage, renders the phosphorus more difficult to oxidize. This enables carboranyl phosphinates to survive harsh oxidizing conditions, a property which is uncommon in organic phosphinates.

carboranes010405 organic chemistryHydrogen bondOrganic Chemistryphosphonateschemistry.chemical_elementAromaticityGeneral ChemistryPhosphinatehydrogen bonding010402 general chemistry01 natural sciencesCatalysis0104 chemical scienceschemistryOxidizing agentCluster (physics)Organic chemistryReactivity (chemistry)ta116CarbonphosphinateshydrophobicityChemistry - A European Journal
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m-Carboranylphosphinate as Versatile Building Blocks To Design all Inorganic Coordination Polymers

2017

The first examples of coordination polymers of manganese(II) and a nickel(II) complex with a purely inorganic carboranylphosphinate ligand are reported, together with its exhaustive characterization. X-ray analysis revealed 1D polymeric chains with carboranylphosphinate ligands bridging two manganese(II) centers. The reactivity of polymer 1 with water and Lewis bases has also been studied Thanks to MINECO (CTQ2015-66143-P, CTQ2010-16237 and SEV-2015-0496), Generalitat de Catalunya (2014/SGR/149), and COST CM1302. E.O. who is enrolled in the PhD program of the UAB thanks for FPU grant

Manganese compoundsInorganic chemistrychemistry.chemical_elementManganese010402 general chemistry01 natural sciencesInorganic ChemistryPolymer chemistrycarboranylphosphinatecoordination complexesLewis acids and basesPhysical and Theoretical Chemistryta116polymerschemistry.chemical_classificationQuímica inorgànica010405 organic chemistryLigandPolymerChemistry Inorganic0104 chemical sciencesNickelManganès -- Compostoscoordination polymerschemistrymanganeseInorganic Chemistry
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CCDC 1534780: Experimental Crystal Structure Determination

2017

Related Article: Elena Oleshkevich, Clara Viñas, Isabel Romero, Duane Choquesillo-Lazarte, Matti Haukka, Francesc Teixidor|2017|Inorg.Chem.|56|5502|doi:10.1021/acs.inorgchem.7b00610

Space GroupCrystallographyCrystal Systemhexaaqua-nickel(ii) bis(17-dicarba-closo-dodecaborane(11)-1-phosphinate)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1434442: Experimental Crystal Structure Determination

2015

Related Article: Elena Oleshkevich, Francesc Teixidor, Duane Choquesillo-Lazarte, Reijo Sillanpää, Clara Viñas|2016|Chem.-Eur.J.|22|3665|doi:10.1002/chem.201504408

Space GroupCrystallographyhexakis(mu2-Aqua)-octa-aqua-tetra-sodium hydrogen 2-methyl-12-dicarba-closo-dodecaboranylphosphinate dihydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1434443: Experimental Crystal Structure Determination

2016

Related Article: Elena Oleshkevich, Francesc Teixidor, Duane Choquesillo-Lazarte, Reijo Sillanpää, Clara Viñas|2016|Chem.-Eur.J.|22|3665|doi:10.1002/chem.201504408

Space GroupCrystallographyCrystal Systemoxonium 1-chlorophosphinato-2-methyl-12-dicarba-closo-dodecaborane(10) monohydrateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1534778: Experimental Crystal Structure Determination

2017

Related Article: Elena Oleshkevich, Clara Viñas, Isabel Romero, Duane Choquesillo-Lazarte, Matti Haukka, Francesc Teixidor|2017|Inorg.Chem.|56|5502|doi:10.1021/acs.inorgchem.7b00610

Space GroupCrystallographytetraaqua-bis(17-dicarba-closo-dodecaborane(11)-1-phosphinato)-manganese(ii) dihydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1534777: Experimental Crystal Structure Determination

2017

Related Article: Elena Oleshkevich, Clara Viñas, Isabel Romero, Duane Choquesillo-Lazarte, Matti Haukka, Francesc Teixidor|2017|Inorg.Chem.|56|5502|doi:10.1021/acs.inorgchem.7b00610

Space GroupCrystallographycatena-[bis(mu-17-dicarba-closo-dodecaborane(11)-1-phosphinato)-bis(methanol)-manganese(ii) methanol solvate]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1534779: Experimental Crystal Structure Determination

2017

Related Article: Elena Oleshkevich, Clara Viñas, Isabel Romero, Duane Choquesillo-Lazarte, Matti Haukka, Francesc Teixidor|2017|Inorg.Chem.|56|5502|doi:10.1021/acs.inorgchem.7b00610

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu-17-dicarba-closo-dodecaborane(11)-1-phosphinato)-(22'-bipyridine)-manganese(ii)]Experimental 3D Coordinates
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CCDC 1434445: Experimental Crystal Structure Determination

2015

Related Article: Elena Oleshkevich, Francesc Teixidor, Duane Choquesillo-Lazarte, Reijo Sillanpää, Clara Viñas|2016|Chem.-Eur.J.|22|3665|doi:10.1002/chem.201504408

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-((mu4-Hydrogen 17-dicarba-closo-dodecaboran-1-ylphosphinato)-(mu3-hydrogen 17-dicarba-closo-dodecaboran-1-ylphosphinato)-(mu2-isopropoxo)-di-sodium)Cell ParametersExperimental 3D Coordinates
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CCDC 1434444: Experimental Crystal Structure Determination

2016

Related Article: Elena Oleshkevich, Francesc Teixidor, Duane Choquesillo-Lazarte, Reijo Sillanpää, Clara Viñas|2016|Chem.-Eur.J.|22|3665|doi:10.1002/chem.201504408

Space GroupCrystallography1-bis(dimethylamino)phosphanyl-12-dicarba-closo-dodecaborane(11)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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