0000000001305009

AUTHOR

Luis Casarrubios

showing 11 related works from this author

Effect of a κ1-Bonded-M-1,2,3-triazole (M = Co, Ru) on the Structure and Reactivity of Group 6 Alkoxy (Fischer) Carbenes

2017

The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.inorgchem. 6b02957. NMR data for the synthesized compounds, electrochemical data of azides 2 and 4 (PDF) Computational details and cif files containing crystal data for 3a and 5b (CIF1, CIF2)

123-Triazole010405 organic chemistryStereochemistryTriazoleAromaticity010402 general chemistry01 natural sciencesMedicinal chemistryCycloaddition0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundchemistryElectrophileAlkoxy groupMoietyReactivity (chemistry)Physical and Theoretical ChemistryInorganic Chemistry 56: 2801-2811 (2017)
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Sequential Reactions of Alkynes on an Iridium(III) Single Site

2017

Sequential insertion of terminal alkynes on IrIII cyclometalated complexes allow the formation of novel metallapolycycles in a controlled and efficient manner. ortho-Methylarylethynyl derivatives led to an unprecedented cascade combination of three fundamental processes (C−C bond formation, C(sp3)−H activation, and reductive coupling) on a single IrIII center, in a process compatible with functionalized biomolecules and photoactive substrates. The reaction with tert-butylacetylene led to a [6,5,4]-polycycle that incorporates an iridacyclobutenylidene in its structure. The sequence is a multicomponent reaction in which the metal not only promotes the different steps but also determines their…

chemistry.chemical_classification010405 organic chemistryBiomoleculeOrganic Chemistrychemistry.chemical_elementSequence (biology)General Chemistry010402 general chemistryPhotochemistry01 natural sciencesCombinatorial chemistryCatalysis0104 chemical sciencesMetalchemistry.chemical_compoundchemistrySingle sitevisual_artvisual_art.visual_art_mediumStereoselectivityIridiumBODIPYSelectivityChemistry - A European Journal
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Triazole-Containing [FeFe] Hydrogenase Mimics: Synthesis and Electrocatalytic Behavior

2019

Through a Cu-catalyzed Huisgen cycloaddition between terminal alkynes and azides (CuAAC) reaction, azide [(μ-SCH2)2N(4-N3C6H4)Fe2(CO)6] has demonstrated to be a robust and versatile reagent able to...

Hydrogenase010405 organic chemistryTriazole010402 general chemistry01 natural sciencesCombinatorial chemistryCycloaddition0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundchemistryReagentAzidePhysical and Theoretical ChemistryInorganic Chemistry
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Revisiting the photochemical synthesis of [FeFe]-hydrogenase mimics: reaction optimization, mechanistic study and electrochemical behaviour

2020

The photoreaction of [(μ-S)2Fe2(CO)6] and alkenes or alkynes has been optimized to readily obtain functionalized [FeFe]-hydrogenase mimics. Irradiation under low CO pressure in THF produces the corresponding photo-adducts in good/acceptable (alkenes/alkynes) yields, with retention of the starting olefin stereochemistry. DFT-calculations provide plausible reaction pathways in both, singlet and triplet states. The DFT-calculation based in the singlet state is energetically more favorable. The electrochemical behavior of the synthesized compounds is also presented, including studies in acidic media. The electrochemical properties of the products vary in the presence of a double bond (cycloaddi…

chemistry.chemical_classificationOlefin fiberHydrogenaseDouble bondchemistryGeneral Chemical EngineeringSingle bondGeneral ChemistrySinglet statePhotochemistryElectrochemistryCycloadditionRSC Advances
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CCDC 1960548: Experimental Crystal Structure Determination

2020

Related Article: Sergio Aguado, Luis Casarrubios, Carmen Ramírez de Arellano, Miguel A. Sierra|2020|RSC Advances|10|29855|doi:10.1039/D0RA06002J

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametershexacarbonyl-{mu-[1-phenyl-34-bis(sulfanyl)pyrrolidine-25-dionato]}-di-ironExperimental 3D Coordinates
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CCDC 1535717: Experimental Crystal Structure Determination

2017

Related Article: Elena A. Giner, Mar Gómez-Gallego, Alba D. Merinero, Luis Casarrubios, Carmen Ramírez de Arellano, Miguel A. Sierra|2017|Chem.-Eur.J.|23|8941|doi:10.1002/chem.201701100

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(eta5-pentamethylcyclopentadienyl)-(34-di-t-butyl-2-{33-dimethyl-1-[2-(pyridin-2-yl)phenyl]butan-12-diyl}cyclobut-2-en-1-ylidene)-iridium tetrakis[35-bis(trifluoromethyl)phenyl]borateExperimental 3D Coordinates
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CCDC 1884097: Experimental Crystal Structure Determination

2019

Related Article: Alba D. Merinero, Alba Collado, Luis Casarrubios, Mar Gómez-Gallego, Carmen Ramírez de Arellano, Antonio Caballero, Fabiola Zapata, Miguel A. Sierra|2019|Inorg.Chem.|58|16267|doi:10.1021/acs.inorgchem.9b02813

Space GroupCrystallographyCrystal SystemCrystal Structure(mu-[(4-azidophenyl)azanediyl]bis(methanethiolato))-hexacarbonyl-di-ironCell ParametersExperimental 3D Coordinates
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CCDC 1536882: Experimental Crystal Structure Determination

2017

Related Article: Elena A. Giner, Mar Gómez-Gallego, Luis Casarrubios, María C. de la Torre, Carmen Ramírez de Arellano, Miguel A. Sierra|2017|Inorg.Chem.|56|2801|doi:10.1021/acs.inorgchem.6b02957

Space GroupCrystallographyCrystal System(mu-ethoxy(5-phenyl-123-triazol-2-yl-4-yl)methylidene)-(14811-tetramethyl-14811-tetraazacyclotetradecane)-pentacarbonyl-cobalt(ii)-chromium(0) perchlorate chloroform solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1884096: Experimental Crystal Structure Determination

2019

Related Article: Alba D. Merinero, Alba Collado, Luis Casarrubios, Mar Gómez-Gallego, Carmen Ramírez de Arellano, Antonio Caballero, Fabiola Zapata, Miguel A. Sierra|2019|Inorg.Chem.|58|16267|doi:10.1021/acs.inorgchem.9b02813

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-[(4-{4-[2-(6-phenyl-9H-purin-9-yl)ethyl]-1H-123-triazol-1-yl}phenyl)azanediyl]bis(methanethiolato))-hexacarbonyl-di-ironExperimental 3D Coordinates
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CCDC 1535716: Experimental Crystal Structure Determination

2017

Related Article: Elena A. Giner, Mar Gómez-Gallego, Alba D. Merinero, Luis Casarrubios, Carmen Ramírez de Arellano, Miguel A. Sierra|2017|Chem.-Eur.J.|23|8941|doi:10.1002/chem.201701100

Space GroupCrystallographyCrystal SystemCrystal Structure((35-dimethyl-2-{2-[2-(pyridin-2-yl)phenyl]ethenyl}phenyl)methyl)-(eta5-pentamethylcyclopentadienyl)-iridium(iii) tetrakis[35-bis(trifluoromethyl)phenyl]borateCell ParametersExperimental 3D Coordinates
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CCDC 1536881: Experimental Crystal Structure Determination

2017

Related Article: Elena A. Giner, Mar Gómez-Gallego, Luis Casarrubios, María C. de la Torre, Carmen Ramírez de Arellano, Miguel A. Sierra|2017|Inorg.Chem.|56|2801|doi:10.1021/acs.inorgchem.6b02957

Space GroupCrystallographyCrystal System(mu-ethoxy(5-phenyl-123-triazol-2-yl-4-yl)methylidene)-(cyclopentadienyl)-((ethane-12-diyl)bis(diphenylphosphine))-pentacarbonyl-ruthenium-tungsten pentane solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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