0000000001306229
AUTHOR
Atanu Dey
Synthesis, Structure, and Magnetic Properties of a Family of Heterometallic Pentanuclear [Co 4 Ln] (Ln = Gd III , Dy III , Tb III , and Ho III ) Assemblies
The reaction of 6-formyl-2-(hydroxymethyl)-4-methylphenol (LH2) with appropriate lanthanide salts followed by reaction with Co(OAc)2·4H2O afforded the pentanuclear heterobimetalllic compounds [Co4Ln(L)4(OAc)2(S)4](NO3)(S) [LnIII = GdIII, S = MeOH (1); LnIII = DyIII, S = H2O (2); LnIII = TbIII, S = MeOH (3); LnIII = HoIII, S = MeOH (4)] in good yields. All the compounds are stable in solution as confirmed by ESI-MS studies. These complexes contain a distorted Co4 tetrahedral core, which encapsulates a central lanthanide ion. The CoII and LnIII ions are in an all-oxygen environments. All the CoII ions possess a distorted octahedral geometry, and the LnIII ions are in a distorted square-antipr…
Heterometallic Pentanuclear [Ni 4 Ln] (Ln III = Gd, Tb, Dy, Ho) Complexes: Accidental Orthogonality Leading to Ferromagnetic Interactions
The reaction of 6-formyl-2-(hydroxymethyl)-4-methylphenol (LH2) with NiII and LnIII salts afforded a series of heterometallic pentanuclear compounds [Ni4Ln(L)4(OAc)2(MeOH)4](NO3)(MeOH) [LnIII = Gd (1), Dy (2), Tb (3), Ho (4)]. Four dianionic L2– ligands and two acetate anions hold together four NiII and one LnIII ion to form a Ni4Ln core possessing a distorted tetrahedral geometry. All the NiII ions are hexacoordinate (6 O) with a distorted octahedral geometry whereas the LnIII ion is octacoordinate (8 O) with a distorted square-antiprism geometry. All the NiII ions are connected to the central LnIII ion through μ2 bridging of one deprotonated phenolic oxygen and two deprotonated alkoxy oxy…
CCDC 927026: Experimental Crystal Structure Determination
Related Article: Vadapalli Chandrasekhar, Sourav Das, Atanu Dey, Sakiat Hossain, Francesc Lloret, Emilio Pardo|2013|Eur.J.Inorg.Chem.||4506|doi:10.1002/ejic.201300413
CCDC 987982: Experimental Crystal Structure Determination
Related Article: Sourav Das, Sakiat Hossain, Atanu Dey, Sourav Biswas, Emilio Pardo, Francesc Lloret, Vadapalli Chandrasekhar|2014|Eur.J.Inorg.Chem.||3393|doi:10.1002/ejic.201402195
CCDC 927025: Experimental Crystal Structure Determination
Related Article: Vadapalli Chandrasekhar, Sourav Das, Atanu Dey, Sakiat Hossain, Francesc Lloret, Emilio Pardo|2013|Eur.J.Inorg.Chem.||4506|doi:10.1002/ejic.201300413
CCDC 987985: Experimental Crystal Structure Determination
Related Article: Sourav Das, Sakiat Hossain, Atanu Dey, Sourav Biswas, Emilio Pardo, Francesc Lloret, Vadapalli Chandrasekhar|2014|Eur.J.Inorg.Chem.||3393|doi:10.1002/ejic.201402195
CCDC 987983: Experimental Crystal Structure Determination
Related Article: Sourav Das, Sakiat Hossain, Atanu Dey, Sourav Biswas, Emilio Pardo, Francesc Lloret, Vadapalli Chandrasekhar|2014|Eur.J.Inorg.Chem.||3393|doi:10.1002/ejic.201402195
CCDC 987984: Experimental Crystal Structure Determination
Related Article: Sourav Das, Sakiat Hossain, Atanu Dey, Sourav Biswas, Emilio Pardo, Francesc Lloret, Vadapalli Chandrasekhar|2014|Eur.J.Inorg.Chem.||3393|doi:10.1002/ejic.201402195
CCDC 927027: Experimental Crystal Structure Determination
Related Article: Vadapalli Chandrasekhar, Sourav Das, Atanu Dey, Sakiat Hossain, Francesc Lloret, Emilio Pardo|2013|Eur.J.Inorg.Chem.||4506|doi:10.1002/ejic.201300413
CCDC 927028: Experimental Crystal Structure Determination
Related Article: Vadapalli Chandrasekhar, Sourav Das, Atanu Dey, Sakiat Hossain, Francesc Lloret, Emilio Pardo|2013|Eur.J.Inorg.Chem.||4506|doi:10.1002/ejic.201300413