0000000001306404
AUTHOR
Pascual Oña-burgos
Cobalt Metal-Organic Framework Based on Layered Double Nanosheets for Enhanced Electrocatalytic Water Oxidation in Neutral Media
A new cobalt metal-organic framework (2D-Co-MOF) based on well-defined layered double cores that are strongly connected by intermolecular bonds has been developed. Its 3D structure is held together by π-π stacking interactions between the labile pyridine ligands of the nanosheets. In aqueous solution, the axial pyridine ligands are exchanged by water molecules, producing a delamination of the material, where the individual double nanosheets preserve their structure. The original 3D layered structure can be restored by a solvothermal process with pyridine, so that the material shows a "memory effect"during the delamination-pillarization process. Electrochemical activation of a 2D-Co-MOF@Nafi…
MOF-Mediated Synthesis of Supported Fe-Doped Pd Nanoparticles under Mild Conditions for Magnetically Recoverable Catalysis**
Metal–organic framework (MOF)-driven synthesis is considered as a promising alternative for the development of new catalytic materials with well-designed active sites. This synthetic approach is used here to gradually transform a new bimetallic MOF, with Pd and Fe as the metal components, by the in situ generation of aniline under mild conditions. This methodology results in a compositionally homogeneous nanocomposite formed by Fe-doped Pd nanoparticles that, in turn, are supported on iron oxide-doped carbon. The nanocomposite has been fully characterized by several techniques such as IR and Raman spectroscopy, TEM, XPS, and XAS. The performance of this nanocomposite as an heterogeneous cat…
CCDC 1910863: Experimental Crystal Structure Determination
Related Article: Sara Sáez-Ferre, Christian W. Lopes, Jorge Simancas, Alejandro Vidal-Moya, Teresa Blasco, Giovanni Agostini, Guillermo Mínguez Espallargas, Jose L. Jordá, Fernando Rey, Pascual Oña-Burgos|2019|Chem.-Eur.J.|25|16390|doi:10.1002/chem.201904043
CCDC 1994492: Experimental Crystal Structure Determination
Related Article: Silvia Gutiérrez-Tarriño, José Luis Olloqui-Sariego, Juan José Calvente, Guillermo Mínguez Espallargas, Fernando Rey, Avelino Corma, Pascual Oña-Burgos|2020|J.Am.Chem.Soc.|142|19198|doi:10.1021/jacs.0c08882
CCDC 1898281: Experimental Crystal Structure Determination
Related Article: Silvia Gutiérrez-Tarriño, José Luis Olloqui-Sariego, Juan José Calvente, Miguel Palomino, Guillermo Mínguez Espallargas, José L. Jordá, Fernando Rey, Pascual Oña-Burgos|2019|ACS Applied Materials and Interfaces|11|46658|doi:10.1021/acsami.9b13655