6533b821fe1ef96bd127c2c1
RESEARCH PRODUCT
MOF-Mediated Synthesis of Supported Fe-Doped Pd Nanoparticles under Mild Conditions for Magnetically Recoverable Catalysis**
Christian W. LopesJaime MazaríoJordan MartinezPascual Oña‐burgosPascual Oña-burgosMónica Giménez-marquésMohanad DarawshehGuillermo Mínguez EspallargasMarcelo Eduardo DomineDebora Motta MeiraDebora Motta Meirasubject
Materials scienceIron09.- Desarrollar infraestructuras resilientes promover la industrialización inclusiva y sostenible y fomentar la innovaciónNanoparticle010402 general chemistryHeterogeneous catalysis01 natural sciences7. Clean energyCatalysisCatalysisNitrobenzenechemistry.chemical_compoundLight sourceAnilineCatàlisiQUIMICA ANALITICAmedia_common.cataloged_instanceUser FacilityEuropean unionBimetallic stripmedia_commonX-ray absorption spectroscopyNanocomposite010405 organic chemistryOrganic ChemistryGeneral ChemistryMetal-organic frameworks0104 chemical sciences12.- Garantizar las pautas de consumo y de producción sostenibleschemistryChemical engineeringFe dopedPd nanoparticlesNanoparticlesMaterials nanoestructuratsNational laboratoryHumanitiesPalladiumdescription
Metal–organic framework (MOF)-driven synthesis is considered as a promising alternative for the development of new catalytic materials with well-designed active sites. This synthetic approach is used here to gradually transform a new bimetallic MOF, with Pd and Fe as the metal components, by the in situ generation of aniline under mild conditions. This methodology results in a compositionally homogeneous nanocomposite formed by Fe-doped Pd nanoparticles that, in turn, are supported on iron oxide-doped carbon. The nanocomposite has been fully characterized by several techniques such as IR and Raman spectroscopy, TEM, XPS, and XAS. The performance of this nanocomposite as an heterogeneous catalyst for hydrogenation of nitroarenes and nitrobenzene coupling with benzaldehyde has been evaluated, proving it to be an efficient and reusable catalyst.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2020-01-01 |