0000000001306566

AUTHOR

Matteo Atzori

showing 10 related works from this author

Synthesis and Physical Properties of K4[Fe(C5O5)2(H2O)2](HC5O5)2·4H2O (C5O52– = Croconate): A Rare Example of Ferromagnetic Coupling via H-bonds

2012

The reaction of the croconate dianion (C(5)O(5))(2-) with a Fe(III) salt has led, unexpectedly, to the formation of the first example of a discrete Fe(II)-croconate complex without additional coligands, K(4)[Fe(C(5)O(5))(2)(H(2)O)(2)](HC(5)O(5))(2)·4H(2)O (1). 1 crystallizes in the monoclinic P2(1)/c space group and presents discrete octahedral Fe(II) complexes coordinated by two chelating C(5)O(5)(2-) anions in the equatorial plane and two trans axial water molecules. The structure can be viewed as formed by alternating layers of trans-diaquabis(croconato)ferrate(II) complexes and layers containing the monoprotonated croconate anions, HC(5)O(5)(-), and noncoordinated water molecules. Both …

Inorganic ChemistryBond lengthCrystallographyMolecular geometryOctahedronChemistryStereochemistryHydrogen bondAntiferromagnetismMoleculeProtonationPhysical and Theoretical ChemistryMonoclinic crystal systemInorganic Chemistry
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A family of layered chiral porous magnets exhibiting tunable ordering temperatures.

2013

A simple change of the substituents in the bridging ligand allows tuning of the ordering temperatures, Tc, in the new family of layered chiral magnets A[M(II)M(III)(X2An)3]·G (A = [(H3O)(phz)3](+) (phz = phenazine) or NBu4(+); X2An(2-) = C6O4X2(2-) = 2,5-dihydroxy-1,4-benzoquinone derivative dianion, with M(III) = Cr, Fe; M(II) = Mn, Fe, Co, etc.; X = Cl, Br, I, H; G = water or acetone). Depending on the nature of X, an increase in Tc from ca. 5.5 to 6.3, 8.2, and 11.0 K (for X = Cl, Br, I, and H, respectively) is observed in the MnCr derivative. Furthermore, the presence of the chiral cation [(H3O)(phz)3](+), formed by the association of a hydronium ion with three phenazine molecules, lead…

010405 organic chemistryHexagonal crystal systemInorganic chemistryPhenazineBridging ligand010402 general chemistry01 natural sciences3. Good health0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryMagnetAcetone[CHIM]Chemical SciencesMoleculePhysical and Theoretical ChemistryPorosityComputingMilieux_MISCELLANEOUSDerivative (chemistry)Inorganic chemistry
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Structural Diversity and Physical Properties of Paramagnetic Molecular Conductors Based on Bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) and the T…

2014

International audience; Electrocrystallization of bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) in the presence of the tris(chloranilato)ferrate(III) [Fe(Cl2An)3]3– paramagnetic chiral anion in different stoichiometric ratios and solvent mixtures afforded three different hybrid systems formulated as [BEDT-TTF]3[Fe(Cl2An)3]·3CH2Cl2·H2O (1), δ-[BEDT-TTF]5[Fe(Cl2An)3]·4H2O (2), and α‴-[BEDT-TTF]18[Fe(Cl2An)3]3·3CH2Cl2·6H2O (3). Compound 1 presents an unusual structure without the typical alternating organic and inorganic layers, whereas compounds 2 and 3show a segregated organic–inorganic crystal structure where layers formed by Λ and Δ enantiomers of the paramagnetic complex, together with…

TrisChemistryInorganic chemistryCrystal structureConductivityInorganic ChemistrySolventCrystallographychemistry.chemical_compoundParamagnetismMolecule[CHIM]Chemical SciencesPhysical and Theoretical ChemistryStoichiometryTetrathiafulvalene
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CCDC 953847: Experimental Crystal Structure Determination

2013

Related Article: Matteo Atzori, Samia Benmansour, Guillermo Mínguez Espallargas, Miguel Clemente-León, Alexandre Abhervé, Patricia Gómez-Claramunt, Eugenio Coronado, Flavia Artizzu, Elisa Sessini, Paola Deplano, Angela Serpe, Maria Laura Mercuri, and Carlos J. Gómez García|2013|Inorg.Chem.|52|10031|doi:10.1021/ic4013284

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[oxonium tris(mu~2~-36-dibromo-45-dioxocyclohexa-26-diene-12-diolato)-chromium-manganese phenazine acetone solvate monohydrate]Experimental 3D Coordinates
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CCDC 996584: Experimental Crystal Structure Determination

2014

Related Article: Matteo Atzori, Flavia Pop, Pascale Auban-Senzier, Carlos J. Gómez-García , Enric Canadell, Flavia Artizzu, Angela Serpe, Paola Deplano, Narcis Avarvari, and Maria Laura Mercuri|2014|Inorg.Chem.|53|7028|doi:10.1021/ic501001r

hexakis(alpha'''-2-(56-Dihydro[13]dithiolo[45-b][14]dithiin-2-ylidene)-56-dihydro[13]dithiolo[45-b][14]dithiine) tris(36-dichloro-45-dioxocyclohexa-26-diene-12-diolato)-iron(iii) dichloromethane solvate dihydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 996582: Experimental Crystal Structure Determination

2014

Related Article: Matteo Atzori, Flavia Pop, Pascale Auban-Senzier, Carlos J. Gómez-García , Enric Canadell, Flavia Artizzu, Angela Serpe, Paola Deplano, Narcis Avarvari, and Maria Laura Mercuri|2014|Inorg.Chem.|53|7028|doi:10.1021/ic501001r

tris(2-(56-Dihydro[13]dithiolo[45-b][14]dithiin-2-ylidene)-56-dihydro[13]dithiolo[45-b][14]dithiin-1-ium) tris(36-dichloro-45-dioxocyclohexa-26-diene-12-diolato)-iron(iii) dichloromethane solvate monohydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 953846: Experimental Crystal Structure Determination

2013

Related Article: Matteo Atzori, Samia Benmansour, Guillermo Mínguez Espallargas, Miguel Clemente-León, Alexandre Abhervé, Patricia Gómez-Claramunt, Eugenio Coronado, Flavia Artizzu, Elisa Sessini, Paola Deplano, Angela Serpe, Maria Laura Mercuri, and Carlos J. Gómez García|2013|Inorg.Chem.|52|10031|doi:10.1021/ic4013284

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-(Oxonium tris(mu~2~-25-dichloro-36-dioxy-14-benzoquinone)-aqua-chromium-manganese tris(phenazine))Cell ParametersExperimental 3D Coordinates
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CCDC 996583: Experimental Crystal Structure Determination

2014

Related Article: Matteo Atzori, Flavia Pop, Pascale Auban-Senzier, Carlos J. Gómez-García , Enric Canadell, Flavia Artizzu, Angela Serpe, Paola Deplano, Narcis Avarvari, and Maria Laura Mercuri|2014|Inorg.Chem.|53|7028|doi:10.1021/ic501001r

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterspentakis(delta-2-(56-Dihydro[13]dithiolo[45-b][14]dithiin-2-ylidene)-56-dihydro[13]dithiolo[45-b][14]dithiine) tris(36-dichloro-45-dioxocyclohexa-26-diene-12-diolato)-iron(iii) tetrahydrateExperimental 3D Coordinates
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CCDC 953848: Experimental Crystal Structure Determination

2013

Related Article: Matteo Atzori, Samia Benmansour, Guillermo Mínguez Espallargas, Miguel Clemente-León, Alexandre Abhervé, Patricia Gómez-Claramunt, Eugenio Coronado, Flavia Artizzu, Elisa Sessini, Paola Deplano, Angela Serpe, Maria Laura Mercuri, and Carlos J. Gómez García|2013|Inorg.Chem.|52|10031|doi:10.1021/ic4013284

Space GroupCrystallographyCrystal Systemcatena-(Oxonium tris(mu~2~-25-dibromo-36-dioxy-14-benzoquinone)-aqua-di-manganese tris(phenazine) monohydrate)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 953849: Experimental Crystal Structure Determination

2013

Related Article: Matteo Atzori, Samia Benmansour, Guillermo Mínguez Espallargas, Miguel Clemente-León, Alexandre Abhervé, Patricia Gómez-Claramunt, Eugenio Coronado, Flavia Artizzu, Elisa Sessini, Paola Deplano, Angela Serpe, Maria Laura Mercuri, and Carlos J. Gómez García|2013|Inorg.Chem.|52|10031|doi:10.1021/ic4013284

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(Tetra-n-butylammonium tris(mu~2~-25-dichloro-36-dioxy-14-benzoquinone)-di-chromium)Experimental 3D Coordinates
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