0000000001306589

AUTHOR

Andreea Dogaru

showing 2 related works from this author

An original 3D coordination polymer constructed from trinuclear nodes and tetracarboxylato spacers

2021

A novel 3D coordination polymer, ∞3[{Cu3(felden)}4(btec)3]·17H2O, has been assembled using cationic trigonal nodes, [CuII3(felden)]3+, generated by a tricompartmental ligand, H3felden, which results from the Schiff condensation reaction between 2,4,6-triformylphloroglucinol and N,N-dimethylethylenediamine. The tetraanion of the 1,2,4,5-benzenetetracaboxylic acid (H4btec) was employed as a spacer. The structure of 1 shows large icosahedral cavities and channels and the magnetic interaction between the copper(II) ions within the triangles is weak and antiferromagnetic.

Materials scienceLigandCoordination polymerIcosahedral symmetryCationic polymerizationchemistry.chemical_elementGeneral ChemistryCondensed Matter PhysicsCondensation reactionCopperIonCrystallographychemistry.chemical_compoundchemistryAntiferromagnetismGeneral Materials ScienceCrystEngComm
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CCDC 2044634: Experimental Crystal Structure Determination

2020

Related Article: Alina S. Dinca, Andreea Dogaru, Adrian E. Ion, Simona Nica, Dan Dumitrescu, Sergiu Shova, Francesc Lloret, Miguel Julve, Marius Andruh|2021|CrystEngComm|23|1332|doi:10.1039/D0CE01667E

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[tetrakis(mu-246-tris({[2-(dimethylamino)ethyl]imino}methyl)benzene-135-triolato)-tris(mu-benzene-1245-tetracarboxylato)-dodeca-copper(ii) unknown solvate]Experimental 3D Coordinates
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