0000000001306796

AUTHOR

Manuel Wilke

showing 5 related works from this author

The crystallisation of copper(ii) phenylphosphonates

2016

The crystal structures and syntheses of four different copper(II) phenylphosphonates, the monophenylphosphonates α-, β-, and γ-Cu(O3PC6H5)·H2O (α-CuPhPmH (1) β-CuPhPmH (2) and γ-CuPhPmH (3)), and the diphosphonate Cu(HO3PC6H5)2·H2O (CuPhP2mH (4)), are presented. The compounds were synthesized from solution at room temperature, at elevated temperature, under hydrothermal conditions, and mechanochemical conditions. The structures of α-CuPhPmH (1) and CuPhP2mH (4) were solved from powder X-ray diffraction data. The structure of β-CuPhPmH (2) was solved by single crystal X-ray analysis. The structures were validated by extended X-ray absorption fine structure (EXAFS) and DTA analyses. Disorder …

Materials scienceExtended X-ray absorption fine structurechemistry.chemical_element02 engineering and technologyCrystal structure010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesCopperHydrothermal circulation0104 chemical scienceslaw.inventionInorganic ChemistryCrystallographyElectron diffractionchemistrylawCrystallizationAbsorption (chemistry)0210 nano-technologySingle crystalDalton Transactions
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Divalent metal phosphonates – new aspects for syntheses, in situ characterization and structure solution

2016

Abstract Divalent metal phosphonates are promising hybrid materials with a broad field of application. The rich coordination chemistry of the phosphonate linkers enables the formation of structures with different dimensionalities ranging from isolated complexes and layered structures to porous frameworks incorporating various functionalities through the choice of the building blocks. In brief, metal phosphonates offer an interesting opportunity for the design of multifunctional materials. Here, we provide a short review on the class of divalent metal phosphonates discussing their syntheses, structures, and applications. We present the advantages of the recently introduced mechanochemical pa…

chemistry.chemical_classificationIn situMaterials science010405 organic chemistry010402 general chemistryCondensed Matter Physics01 natural sciencesPhosphonateCombinatorial chemistry0104 chemical sciencesCharacterization (materials science)Coordination complexDivalentInorganic ChemistryMetalchemistry.chemical_compoundchemistryMechanochemistryvisual_artvisual_art.visual_art_mediumOrganic chemistryGeneral Materials ScienceHybrid materialZeitschrift für Kristallographie - Crystalline Materials
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CCDC 1490687: Experimental Crystal Structure Determination

2016

Related Article: Manuel Wilke, Anke Kabelitz, Tatiana E. Gorelik, Ana Guilherme Buzanich, Uwe Reinholz, Ute Kolb, Klaus Rademann, Franziska Emmerling|2016|Dalton Trans.|45|17453|doi:10.1039/C6DT02904C

Space GroupCrystallographyCrystal Systemcatena-[(mu-phenylphosphonato)-aqua-copper(ii)]Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1490689: Experimental Crystal Structure Determination

2016

Related Article: Manuel Wilke, Anke Kabelitz, Tatiana E. Gorelik, Ana Guilherme Buzanich, Uwe Reinholz, Ute Kolb, Klaus Rademann, Franziska Emmerling|2016|Dalton Trans.|45|17453|doi:10.1039/C6DT02904C

Space GroupCrystallographyCrystal Systemcatena-[(mu-aqua)-bis(mu-hydrogen phenylphosphonato)-copper(ii)]Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1490688: Experimental Crystal Structure Determination

2016

Related Article: Manuel Wilke, Anke Kabelitz, Tatiana E. Gorelik, Ana Guilherme Buzanich, Uwe Reinholz, Ute Kolb, Klaus Rademann, Franziska Emmerling|2016|Dalton Trans.|45|17453|doi:10.1039/C6DT02904C

Space GroupCrystallographyCrystal Systemcatena-[(mu-phenylphosphonato)-aqua-copper(ii)]Crystal StructureCell ParametersExperimental 3D Coordinates
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