0000000001306840
AUTHOR
Reum Scott
Reversible switching of the electronic ground state in a pentacoordinated Cu(ii) complex.
International audience; An easy reversible switching of the electronic ground state in a pentacoordinated copper(ii) complex is reported for the first time. The simple protonation of a carboxylic group in a Cu(ii) complex with a {dx(2)-y(2)}(1) electronic configuration leads to a flip of the ground electronic configuration from {dx(2)-y(2)}(1) to {dz(2)}(1) in the metal ion.
CCDC 881999: Experimental Crystal Structure Determination
Related Article: Ashok Sasmal,Sandeepta Saha,Carlos J. Gomez-Garcia,Cedric Desplanches,Eugenio Garribba,Antonio Bauza,Antonio Frontera,Reum Scott,Ray J. Butcher,Samiran Mitra|2013|Chem.Commun.|49|7806|doi:10.1039/C3CC44276D