0000000001307191

AUTHOR

Andrew J. P. White

showing 8 related works from this author

Ex Vivo Tracking of Endogenous CO with a Ruthenium(II) Complex.

2017

[EN] A two-photon fluorescent probe based on a ruthenium(II) vinyl complex is capable of selectively detecting carbon monoxide in cells and ex vivo using mice with a subcutaneous air pouch as a model for inflammation. This probe combines highly selective and sensitive ex vivo detection of endogenous CO in a realistic model with facile, inexpensive synthesis, and displays many advantages over the widely used palladium-based systems.

StereochemistryChemistry MultidisciplinaryFLUORESCENT-PROBEFluorescent-Probechemistry.chemical_elementCarbonylationEndogeny010402 general chemistryFluorogenic probes01 natural sciencesBiochemistryCatalysischemistry.chemical_compoundQUIMICA ORGANICAColloid and Surface ChemistrySelective detectionQUIMICA ANALITICACarbon-MonoxideLIVING CELLSCARBON-MONOXIDEScience & Technology010405 organic chemistryAirSELECTIVE DETECTIONFLUOROGENIC PROBESAIRQUIMICA INORGANICACARBONYLATIONLiving cellsGeneral ChemistryFluorescence0104 chemical sciencesRutheniumChemistrychemistryPhysical SciencesBiophysicsSubcutaneous airHEME OXYGENASE-103 Chemical SciencesCarbonylationHeme Oxygenase-1Ex vivoCarbon monoxidePalladiumJournal of the American Chemical Society
researchProduct

Tuning Azoheteroarene Photoswitch Performance through Heteroaryl Design

2017

International audience; Photoswitchable compounds, which can be reversibly switched between two isomers by light, continue to attract significant attention for a wide array of applications. Azoheteroarenes represent a relatively new but understudied type of photoswitch, where one of the aryl rings from the conventional azobenzene class has been replaced with a five-membered heteroaromatic ring. Initial studies have suggested the azoheteroarenes – the arylazopyrazoles in particular – to have excellent photoswitching properties (quantitative switching and long Z isomer half-life). Here we present a systematic computational and experimental study to elucidate the origin of the long thermal hal…

CHEMICAL-REACTIONSMOLECULAR SWITCHESFUNCTIONAL RESPONSE THEORYChemistry Multidisciplinary010402 general chemistryRing (chemistry)Photochemistry01 natural sciencesBiochemistryCatalysischemistry.chemical_compoundColloid and Surface ChemistryAZO-COMPOUNDSPHOTOISOMERIZATION[CHIM]Chemical SciencesTO-TRANS ISOMERIZATIONAZOBENZENEScience & TechnologyPhotoswitch010405 organic chemistryArylSOLAR THERMAL STORAGEGeneral ChemistryCombinatorial chemistry0104 chemical sciencesChemistrychemistryAzobenzenePhysical SciencesEXCITATION-ENERGIESVISIBLE-LIGHT03 Chemical Sciences
researchProduct

CCDC 1503532: Experimental Crystal Structure Determination

2017

Related Article: Joaquín Calbo, Claire E. Weston, Andrew J. P. White, Henry S. Rzepa, Julia Contreras-García, Matthew J. Fuchter|2017|J.Am.Chem.Soc.|139|1261|doi:10.1021/jacs.6b11626

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters14-dimethyl-3-nitro-1H-pyrazoleExperimental 3D Coordinates
researchProduct

CCDC 1498393: Experimental Crystal Structure Determination

2018

Related Article: Cristina de la Torre, Anita Toscani, Cristina Marín-Hernández, Jonathan A. Robson, María Carmen Terencio, Andrew J. P. White, María José Alcaraz, James D. E. T. Wilton-Ely, Ramón Martínez-Máñez, Félix Sancenón|2017|J.Am.Chem.Soc.|139|18484|doi:10.1021/jacs.7b11158

carbonyl-(chloro)-(2-(9-phenanthryl)vinyl)-(5-(3-thienyl)-213-benzothiadiazole)-bis(triphenylphosphine)-ruthenium(ii) dichloromethane solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1498394: Experimental Crystal Structure Determination

2018

Related Article: Cristina de la Torre, Anita Toscani, Cristina Marín-Hernández, Jonathan A. Robson, María Carmen Terencio, Andrew J. P. White, María José Alcaraz, James D. E. T. Wilton-Ely, Ramón Martínez-Máñez, Félix Sancenón|2017|J.Am.Chem.Soc.|139|18484|doi:10.1021/jacs.7b11158

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersdicarbonyl-(chloro)-(2-(9-phenanthryl)vinyl)-bis(triphenylphosphine)-ruthenium(ii) dichloromethane solvateExperimental 3D Coordinates
researchProduct

CCDC 1503530: Experimental Crystal Structure Determination

2017

Related Article: Joaquín Calbo, Claire E. Weston, Andrew J. P. White, Henry S. Rzepa, Julia Contreras-García, Matthew J. Fuchter|2017|J.Am.Chem.Soc.|139|1261|doi:10.1021/jacs.6b11626

Space GroupCrystallographyCrystal System1-methyl-3-(phenyldiazenyl)-1H-124-triazoleCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1503531: Experimental Crystal Structure Determination

2017

Related Article: Joaquín Calbo, Claire E. Weston, Andrew J. P. White, Henry S. Rzepa, Julia Contreras-García, Matthew J. Fuchter|2017|J.Am.Chem.Soc.|139|1261|doi:10.1021/jacs.6b11626

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates1-methyl-4-(phenyldiazenyl)-1H-imidazole
researchProduct

CCDC 1498392: Experimental Crystal Structure Determination

2018

Related Article: Cristina de la Torre, Anita Toscani, Cristina Marín-Hernández, Jonathan A. Robson, María Carmen Terencio, Andrew J. P. White, María José Alcaraz, James D. E. T. Wilton-Ely, Ramón Martínez-Máñez, Félix Sancenón|2017|J.Am.Chem.Soc.|139|18484|doi:10.1021/jacs.7b11158

Space GroupCrystallographyCrystal System5-(3-thienyl)-213-benzothiadiazoleCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct