0000000001307322

AUTHOR

V. Kinzhybalo

showing 4 related works from this author

A crucial role of adamantanoid Cu(II) complexes in the redox systems: CuCl–diallylsulfoxide–O2 and CuCl2–diallylsulfide–O2

2014

Abstract The hypothetically reversible [Cu(I)(diallylsulfoxide)] ↔ O 2 [Cu(II)(diallylsulfide)] system was examined by FTIR spectroscopy and X-ray diffraction. It is stated that the Cu4OCl6 body centered adamantanoid cages, appearing at both the substrate and product sites, act as a template to promote the oxidation of diallylsulfide to diallylsulfoxide or Cu(I) to Cu(II), thus making the reaction irreversible. Each of these two adamantanoid cores possesses a different point symmetry as well as self assembly mode to form two polymorphs of the [Cu4OCl6(diallylsulfoxide)4] complex. Their polymorphic relationships based on the symmetry homology S4 ← Td → C3, as well as the distortion in the Cu…

O-body centered adamantanoid cagestructural homologyDiallylsulfideChemistryPoint symmetrydiallylsulfide oxidationRedoxpolymorphismInorganic ChemistryStructural homologyCrystallographyPolymorphism (materials science)Materials ChemistrySelf-assemblyPhysical and Theoretical ChemistryFourier transform infrared spectroscopyCoordination geometryPolyhedron
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CCDC 922699: Experimental Crystal Structure Determination

2014

Related Article: V.V. Olijnyk, B. Zarychta, V. Kinzhybalo|2014|Polyhedron|69|234|doi:10.1016/j.poly.2013.11.040

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu4-Oxo)-hexakis(mu2-chloro)-tetrakis(diallylsulfoxide)-tetra-copper(ii)Experimental 3D Coordinates
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CCDC 708298: Experimental Crystal Structure Determination

2010

Related Article: T.Duzak, V.Kinzhybalo, K.Slepokura, V.Olijnyk|2009|Z.Anorg.Allg.Chem.|635|2324|doi:10.1002/zaac.200801362

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-((mu~5~-Chloro)-(mu~4~-eta^2^-tetra-allylsilane)-tris(mu~3~-chloro)-(mu~2~-chloro)-penta-copper)Experimental 3D Coordinates
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CCDC 922698: Experimental Crystal Structure Determination

2014

Related Article: V.V. Olijnyk, B. Zarychta, V. Kinzhybalo|2014|Polyhedron|69|234|doi:10.1016/j.poly.2013.11.040

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu4-Oxo)-hexakis(mu2-chloro)-tetrakis(diallylsulfoxide)-tetra-copper(ii)Experimental 3D Coordinates
researchProduct