0000000001307324

AUTHOR

Víctor Fariña-torres

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Heterometallic palladium-iron metal-organic framework as a highly active catalyst for cross-coupling reactions.

2022

Palladium-based metal-organic frameworks (Pd-MOFs) are an emerging class of heterogeneous catalysts extremely challenging to achieve due to the facile leaching of palladium and its tendency to be reduced. Herein, Pd(II) was successfully incorporated in the framework of a MOF denoted as MUV-22 using a solvent assisted reaction. This stable MOF, with square-octahedron (soc) topology as MIL-127, and a porosity of 710 m2 g−1, is highly active, selective, and recyclable for the Suzuki-Miyaura allylation of aryl and alkyl boronates as exemplified with the coupling between cinnamyl bromide and Me-Bpin, a typically reluctant reagent in cross-coupling reactions.

General ChemistryMetalls de transicióReaccions químiquesChemical science
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CCDC 2131105: Experimental Crystal Structure Determination

2022

Related Article: Eugenia Miguel-Casañ, Mohanad D. Darawsheh, Víctor Fariña-Torres, Iñigo J. Vitórica-Yrezábal, Eduardo Andres-Garcia, Martín Fañanás-Mastral, Guillermo Mínguez Espallargas|2023|Chemical Science|14|179|doi:10.1039/D2SC05192C

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[hexakis(mu-pyridine-35-dicarboxylato)-bis(mu-oxo)-hexa-aqua-hexachloro-hexa-iron-tri-palladium unknown solvate hexahydrate]Experimental 3D Coordinates
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