0000000001307511

AUTHOR

Marina Huth

showing 4 related works from this author

Chasing Weak Forces: Hierarchically Assembled Helicates as a Probe for the Evaluation of the Energetics of Weak Interactions.

2017

London dispersion forces are the weakest interactions between molecules. Because of this, their influence on chemical processes is often low, but can definitely not be ignored, and even becomes important in cases of molecules with large contact surfaces. Hierarchically assembled dinuclear titanium(IV) helicates represent a rare example in which the direct observation of London dispersion forces is possible in solution even in the presence of strong cohesive solvent effects. Hereby, the dispersion forces do not unlimitedly support the formation of the dimeric complexes. Although they have some favorable enthalpic contribution to the dimerization of the monomeric complex units, large flexible…

sondit010405 organic chemistryChemistryStereochemistryDirect observationhelicatesGeneral ChemistryWeak interactioninteractions010402 general chemistry01 natural sciencesBiochemistryLondon dispersion forceCatalysis0104 chemical scienceschemistry.chemical_compoundColloid and Surface ChemistryMonomerContact surfacesChemical physicsweak forcesMoleculeSolvent effectsprobesta116Journal of the American Chemical Society
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CCDC 1539540: Experimental Crystal Structure Determination

2020

Related Article: David Van Craen, Wolfgang H. Rath, Marina Huth, Laura Kemp, Christoph Räuber, Jan M. Wollschläger, Christoph A. Schalley, Arto Valkonen, Kari Rissanen, Markus Albrecht|2017|J.Am.Chem.Soc.|139|16959|doi:10.1021/jacs.7b10098

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[hexakis(mu-3-[(cyclobutyloxy)carbonyl]benzene-12-bis(olato))-bis(methanol)-tetra-lithium-di-titanium diethyl ether solvate]Cell ParametersExperimental 3D Coordinates
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CCDC 1539541: Experimental Crystal Structure Determination

2020

Related Article: David Van Craen, Wolfgang H. Rath, Marina Huth, Laura Kemp, Christoph Räuber, Jan M. Wollschläger, Christoph A. Schalley, Arto Valkonen, Kari Rissanen, Markus Albrecht|2017|J.Am.Chem.Soc.|139|16959|doi:10.1021/jacs.7b10098

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatesoxonium dodecakis(mu-cyclopentyl 23-dioxybenzoate)-bis(methanol)-hepta-lithium-tetra-titanium diethyl ether methanol solvate hydrate
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CCDC 1539539: Experimental Crystal Structure Determination

2020

Related Article: David Van Craen, Wolfgang H. Rath, Marina Huth, Laura Kemp, Christoph Räuber, Jan M. Wollschläger, Christoph A. Schalley, Arto Valkonen, Kari Rissanen, Markus Albrecht|2017|J.Am.Chem.Soc.|139|16959|doi:10.1021/jacs.7b10098

Space GroupCrystallographyCrystal Systembis(mu-NN-dimethylformamide)-tetrakis(NN-dimethylformamide)-di-lithium bis(hexakis(mu-3-(ethoxycarbonyl)benzene-12-bis(olato))-tri-lithium-di-titanium)Crystal StructureCell ParametersExperimental 3D Coordinates
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