0000000001307953
AUTHOR
José M. Seco
In vitro evaluation of leishmanicidal properties of a new family of monodimensional coordination polymers based on diclofenac ligand
Some series of isostructural chains with general formula [M(diclof)(HO)]·(EtOH) have been obtained from reaction between diclofenac ligand (diclof) and first row transition salts (M = Mn (1),Ni (2) and Co (3)). These monodimensional coordination polymers have been characterized and their crystal structures have been solved by X-ray diffraction methods, elucidating isostructural compounds that are chains with water molecules acting as bridge between different metallic centers, while diclofenac ligands are coordinated to the octahedral coordination environment of the same. Magnetic studies of these complexes have revealed the existence of moderate ferromagnetic interactions among manganese, n…
Influence of thermally induced structural transformations on the magnetic and luminescence properties of tartrate-based chiral lanthanide organic-frameworks
This work reports on the synthesis and characterization of five enantiomeric pairs of isostructural 3D metal-organic frameworks (MOFs) with the general formula {[Ln2(μ4-tar)2(μ-tar)(H2O)2]·xH2O}n [where Ln(iii) = Tb (Tb-L and Tb-D), Dy (Dy-L and Dy-D), Ho (Ho-L and Ho-D), Er (Er-L and Er-D) and Tm (Tm-L and Tm-D); tar = tartrate (d- or l-) and x = 3 or 4 depending on the counterpart], which possess interesting luminescence and magnetic properties. These MOFs undergo progressive and reversible dehydration processes upon controlled heating yielding three crystalline phases (Ln-L′, Ln-L′′ and Ln-L′′′). Alternating current magnetic measurements on Tb, Dy and Er-based compounds exhibit field ind…
Influence of the anions on the structure and magnetic properties of a series of bis(µ-diphexono)-bridged linear trinuclear copper(II) complexes: an experimental and theoretical study
The reaction of H(2)L (N,N'-dimethyl-N,N'-bis(2-hydroxy-3-methoxy-5-methylbenzyl)-ethylenediamine) with different copper salts, in methanol and using a H(2)L/Cu = 2 : 3 molar ratio, led to four new bis(μ-diphenoxo)-bridged Cu(3) complexes of general formula [{Cu(S)(μ-L)}(2)Cu(H(2)O)(2n)]X(2) (S = CH(3)OH, n = 1 and X = BF(4)(-) for (1) or ClO(4)(-) for (2); S = Br(3)(-) anion and n = 1 without any X species for (3); S = H(2)O, n = 0 and X = NO(3)(-) for (4)). The use in the same reaction conditions of 4,4'-bipyridine (4,4'-bipy) as connector led to the chain complex [{Cu(μ-4,4'-bipy)(0.5)(μ-L)}(2)Cu(H(2)O)(2n)](ClO(4))(2)·17H(2)O (5). The structure of the centrosymmetric trinuclear unit in …
CCDC 1981579: Experimental Crystal Structure Determination
Related Article: Uxua Huizi-Rayo, Andoni Zabala-Lekuona, Alessio Terenzi, Carlos M. Cruz, Juan M. Cuerva, Antonio Rodríguez-Diéguez, Jose Angel García, José M. Seco, Eider San Sebastian, Javier Cepeda|2020|J.Mater.Chem.C|8|8243|doi:10.1039/D0TC00736F
CCDC 1884201: Experimental Crystal Structure Determination
Related Article: Amalia García-García, José M. Méndez-Arriaga, Rubén Martín-Escolano, Javier Cepeda, Santiago Gómez-Ruiz, Alfonso Salinas-Castillo, José M. Seco, Manuel Sánchez-Moreno, Duane Choquesillo-Lazarte, Ana B. Ruiz-Muelle, Ignacio Fernández, Clotilde Marín, Antonio Rodríguez-Diéguez|2020|Polyhedron|184|114570|doi:10.1016/j.poly.2020.114570
CCDC 1981582: Experimental Crystal Structure Determination
Related Article: Uxua Huizi-Rayo, Andoni Zabala-Lekuona, Alessio Terenzi, Carlos M. Cruz, Juan M. Cuerva, Antonio Rodríguez-Diéguez, Jose Angel García, José M. Seco, Eider San Sebastian, Javier Cepeda|2020|J.Mater.Chem.C|8|8243|doi:10.1039/D0TC00736F
CCDC 1981573: Experimental Crystal Structure Determination
Related Article: Uxua Huizi-Rayo, Andoni Zabala-Lekuona, Alessio Terenzi, Carlos M. Cruz, Juan M. Cuerva, Antonio Rodríguez-Diéguez, Jose Angel García, José M. Seco, Eider San Sebastian, Javier Cepeda|2020|J.Mater.Chem.C|8|8243|doi:10.1039/D0TC00736F
CCDC 1981583: Experimental Crystal Structure Determination
Related Article: Uxua Huizi-Rayo, Andoni Zabala-Lekuona, Alessio Terenzi, Carlos M. Cruz, Juan M. Cuerva, Antonio Rodríguez-Diéguez, Jose Angel García, José M. Seco, Eider San Sebastian, Javier Cepeda|2020|J.Mater.Chem.C|8|8243|doi:10.1039/D0TC00736F
CCDC 1981580: Experimental Crystal Structure Determination
Related Article: Uxua Huizi-Rayo, Andoni Zabala-Lekuona, Alessio Terenzi, Carlos M. Cruz, Juan M. Cuerva, Antonio Rodríguez-Diéguez, Jose Angel García, José M. Seco, Eider San Sebastian, Javier Cepeda|2020|J.Mater.Chem.C|8|8243|doi:10.1039/D0TC00736F
CCDC 1981577: Experimental Crystal Structure Determination
Related Article: Uxua Huizi-Rayo, Andoni Zabala-Lekuona, Alessio Terenzi, Carlos M. Cruz, Juan M. Cuerva, Antonio Rodríguez-Diéguez, Jose Angel García, José M. Seco, Eider San Sebastian, Javier Cepeda|2020|J.Mater.Chem.C|8|8243|doi:10.1039/D0TC00736F
CCDC 1981578: Experimental Crystal Structure Determination
Related Article: Uxua Huizi-Rayo, Andoni Zabala-Lekuona, Alessio Terenzi, Carlos M. Cruz, Juan M. Cuerva, Antonio Rodríguez-Diéguez, Jose Angel García, José M. Seco, Eider San Sebastian, Javier Cepeda|2020|J.Mater.Chem.C|8|8243|doi:10.1039/D0TC00736F
CCDC 1884200: Experimental Crystal Structure Determination
Related Article: Amalia García-García, José M. Méndez-Arriaga, Rubén Martín-Escolano, Javier Cepeda, Santiago Gómez-Ruiz, Alfonso Salinas-Castillo, José M. Seco, Manuel Sánchez-Moreno, Duane Choquesillo-Lazarte, Ana B. Ruiz-Muelle, Ignacio Fernández, Clotilde Marín, Antonio Rodríguez-Diéguez|2020|Polyhedron|184|114570|doi:10.1016/j.poly.2020.114570
CCDC 1981581: Experimental Crystal Structure Determination
Related Article: Uxua Huizi-Rayo, Andoni Zabala-Lekuona, Alessio Terenzi, Carlos M. Cruz, Juan M. Cuerva, Antonio Rodríguez-Diéguez, Jose Angel García, José M. Seco, Eider San Sebastian, Javier Cepeda|2020|J.Mater.Chem.C|8|8243|doi:10.1039/D0TC00736F
CCDC 1981575: Experimental Crystal Structure Determination
Related Article: Uxua Huizi-Rayo, Andoni Zabala-Lekuona, Alessio Terenzi, Carlos M. Cruz, Juan M. Cuerva, Antonio Rodríguez-Diéguez, Jose Angel García, José M. Seco, Eider San Sebastian, Javier Cepeda|2020|J.Mater.Chem.C|8|8243|doi:10.1039/D0TC00736F
CCDC 1981572: Experimental Crystal Structure Determination
Related Article: Uxua Huizi-Rayo, Andoni Zabala-Lekuona, Alessio Terenzi, Carlos M. Cruz, Juan M. Cuerva, Antonio Rodríguez-Diéguez, Jose Angel García, José M. Seco, Eider San Sebastian, Javier Cepeda|2020|J.Mater.Chem.C|8|8243|doi:10.1039/D0TC00736F
CCDC 1981571: Experimental Crystal Structure Determination
Related Article: Uxua Huizi-Rayo, Andoni Zabala-Lekuona, Alessio Terenzi, Carlos M. Cruz, Juan M. Cuerva, Antonio Rodríguez-Diéguez, Jose Angel García, José M. Seco, Eider San Sebastian, Javier Cepeda|2020|J.Mater.Chem.C|8|8243|doi:10.1039/D0TC00736F
CCDC 1981574: Experimental Crystal Structure Determination
Related Article: Uxua Huizi-Rayo, Andoni Zabala-Lekuona, Alessio Terenzi, Carlos M. Cruz, Juan M. Cuerva, Antonio Rodríguez-Diéguez, Jose Angel García, José M. Seco, Eider San Sebastian, Javier Cepeda|2020|J.Mater.Chem.C|8|8243|doi:10.1039/D0TC00736F
CCDC 1981576: Experimental Crystal Structure Determination
Related Article: Uxua Huizi-Rayo, Andoni Zabala-Lekuona, Alessio Terenzi, Carlos M. Cruz, Juan M. Cuerva, Antonio Rodríguez-Diéguez, Jose Angel García, José M. Seco, Eider San Sebastian, Javier Cepeda|2020|J.Mater.Chem.C|8|8243|doi:10.1039/D0TC00736F