0000000001308099
AUTHOR
Elena Badetti
Organic Polyradicals as Redox Mediators: Effect of Intramolecular Radical Interactions on Their Efficiency
The spin–spin interactions between unpaired electrons in organic (poly)radicals, especially nitroxides, are largely investigated and are of crucial importance for their applications in areas such as organic magnetism, molecular charge transfer, or multiple spin labeling in structural biology. Recently, 2,2,6,6-tetramethylpiperidinyloxyl and polymers functionalized with nitroxides have been described as successful redox mediators in several electrochemical applications; however, the study of spin–spin interaction effect in such an area is absent. This communication reports the preparation of a novel family of discrete polynitroxide molecules, with the same number of radical units but differe…
Binding Profiles of Self-Assembled Supramolecular Cages from ESI-MS Based Methodology
Confined molecular environments have peculiar characteristics that make their properties unique in the field of biological and chemical sciences. In recent years, advances in supramolecular capsule and cage synthesis have presented the possibility to interpret the principles behind their self‐assembly and functions, which has led to new molecular systems that display outstanding properties in molecular recognition and catalysis. Herein, we report a rapid method based on ESI‐MS to determine the binding profiles for linear saturated dicarboxylic acids in a series of different cages. The cages were obtained by self‐assembly of modified tris(pyridylmethyl)amine (TPMA) complexes and diamines cho…
CCDC 1986124: Experimental Crystal Structure Determination
Related Article: Elena Badetti, Vega Lloveras, Emanuele Amadio, Rosalia Di Lorenzo, Mara Olivares-Marín, Alvaro Y. Tesio, Songbai Zhang, Fangfang Pan, Kari Rissanen, Jaume Veciana, Dino Tonti, Jose Vidal-Gancedo, Cristiano Zonta, Giulia Licini|2020|ACS Applied Materials and Interfaces|12|45968|doi:10.1021/acsami.0c09386
CCDC 1424389: Experimental Crystal Structure Determination
Related Article: Carlo Bravin, Elena Badetti, Rakesh Puttreddy, Fangfang Pan, Kari Rissanen, Giulia Licini, Cristiano Zonta|2018|Chem.-Eur.J.|24|2936|doi:10.1002/chem.201704725
CCDC 1424391: Experimental Crystal Structure Determination
Related Article: Carlo Bravin, Elena Badetti, Rakesh Puttreddy, Fangfang Pan, Kari Rissanen, Giulia Licini, Cristiano Zonta|2018|Chem.-Eur.J.|24|2936|doi:10.1002/chem.201704725
CCDC 1424390: Experimental Crystal Structure Determination
Related Article: Carlo Bravin, Elena Badetti, Rakesh Puttreddy, Fangfang Pan, Kari Rissanen, Giulia Licini, Cristiano Zonta|2018|Chem.-Eur.J.|24|2936|doi:10.1002/chem.201704725