0000000001308630
AUTHOR
Pablo J. Bereciartua
A fluorinated 2D magnetic coordination polymer
Herein we show the versatility of coordination chemistry to design and expand a family of 2D materials by incorporating F groups at the surface of the layers. Through the use of a prefuntionalized organic linker with F groups, it is possible to achieve a layered magnetic material based on Fe(ii) centers that are chemically stable in open air, contrary to the known 2D inorganic magnetic materials. The high quality of the single crystals and their robustness allow to fabricate 2D molecular materials by micromechanical exfoliation, preserving the crystalline nature of these layers together with the desired functionalization.
CCDC 1582351: Experimental Crystal Structure Determination
Related Article: Javier López-Cabrelles, Samuel Mañas-Valero, Iñigo J. Vitórica-Yrezábal, Pablo J. Bereciartua, Eugenio Coronado, Guillermo Mínguez Espallargas|2022|Dalton Trans.|51|1861|doi:10.1039/D1DT03734J