Author: Fabian Mohr

0000000001308901

AUTHOR

Fabian Mohr

Acylchalcogenourea Complexes of Silver(I)

Acylthio- or acylselenoureas react with silver(I) oxide to form tetranuclear silver(I) complexes containing the deprotonated acylchalcogenourea ligands bound to the silver atoms through the chalcogen and oxygen atoms. These tetrasilver(I) species react with either 4 or 8 equiv. of a phosphine to afford either dinuclear silver(I) phosphine complexes or tetrahedral silver diphosphine complexes. In these compounds, the acylchalcogenourea ligands form six-membered rings by coordinating to the metal atom through the chalcogen and oxygen atoms. In one case, we observed a very rare example of an acylthiourea ligand coordinated through the nitrogen and sulfur atoms to form a four-membered ring. A s…

research product

CCDC 1513652: Experimental Crystal Structure Determination

Related Article: Maik Dörner, J. Mikko Rautiainen, Jörg Rust, Christian W. Lehmann, Fabian Mohr|2017|Eur.J.Inorg.Chem.||789|doi:10.1002/ejic.201601074

research product

CCDC 1513654: Experimental Crystal Structure Determination

Related Article: Maik Dörner, J. Mikko Rautiainen, Jörg Rust, Christian W. Lehmann, Fabian Mohr|2017|Eur.J.Inorg.Chem.||789|doi:10.1002/ejic.201601074

research product

CCDC 1513650: Experimental Crystal Structure Determination

Related Article: Maik Dörner, J. Mikko Rautiainen, Jörg Rust, Christian W. Lehmann, Fabian Mohr|2017|Eur.J.Inorg.Chem.||789|doi:10.1002/ejic.201601074

research product

CCDC 1513656: Experimental Crystal Structure Determination

Related Article: Maik Dörner, J. Mikko Rautiainen, Jörg Rust, Christian W. Lehmann, Fabian Mohr|2017|Eur.J.Inorg.Chem.||789|doi:10.1002/ejic.201601074

research product

CCDC 1406811: Experimental Crystal Structure Determination

Related Article: Maik Dörner, J. Mikko Rautiainen, Jörg Rust, Christian W. Lehmann, Fabian Mohr|2017|Eur.J.Inorg.Chem.||789|doi:10.1002/ejic.201601074

research product

CCDC 1513651: Experimental Crystal Structure Determination

Related Article: Maik Dörner, J. Mikko Rautiainen, Jörg Rust, Christian W. Lehmann, Fabian Mohr|2017|Eur.J.Inorg.Chem.||789|doi:10.1002/ejic.201601074

research product

CCDC 1513655: Experimental Crystal Structure Determination

Related Article: Maik Dörner, J. Mikko Rautiainen, Jörg Rust, Christian W. Lehmann, Fabian Mohr|2017|Eur.J.Inorg.Chem.||789|doi:10.1002/ejic.201601074

research product

CCDC 1513653: Experimental Crystal Structure Determination

Related Article: Maik Dörner, J. Mikko Rautiainen, Jörg Rust, Christian W. Lehmann, Fabian Mohr|2017|Eur.J.Inorg.Chem.||789|doi:10.1002/ejic.201601074

research product

PEPhysical Sciences and Engineering
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LSLife Sciences
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