0000000001309096

AUTHOR

Alfonso Salinas-castillo

showing 4 related works from this author

In vitro evaluation of leishmanicidal properties of a new family of monodimensional coordination polymers based on diclofenac ligand

2020

Some series of isostructural chains with general formula [M(diclof)(HO)]·(EtOH) have been obtained from reaction between diclofenac ligand (diclof) and first row transition salts (M = Mn (1),Ni (2) and Co (3)). These monodimensional coordination polymers have been characterized and their crystal structures have been solved by X-ray diffraction methods, elucidating isostructural compounds that are chains with water molecules acting as bridge between different metallic centers, while diclofenac ligands are coordinated to the octahedral coordination environment of the same. Magnetic studies of these complexes have revealed the existence of moderate ferromagnetic interactions among manganese, n…

chemistry.chemical_classificationDiclofenac010405 organic chemistryLigandMagnetismChainschemistry.chemical_elementTransition metalsCrystal structure010402 general chemistry01 natural sciences0104 chemical sciencesCoordination complexInorganic ChemistryCrystallographyNickelTransition metalchemistryOctahedronMaterials ChemistryMoleculePhysical and Theoretical ChemistryIsostructuralLeishmaniasisPolyhedron
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Novel metal–organic frameworks based on 5-bromonicotinic acid: Multifunctional materials with H2 purification capabilities

2012

Two new metal–organic frameworks based on 5-bromonicotinic acid complexes [Cd(5-BrNic)2]n (1) and [Co(5-BrNic)2(H2O)]n (2) have been synthesized by hydrothermal reactions of this ligand with cadmium and cobalt metallic(II) salts in the presence of water. Compound 1 displays intense photoluminescence properties in the solid state at room temperature, while 2 exhibits an antiferromagnetic interaction between Co(II) ions with a J value of −4.1 cm−1. Experimental studies, backed up by Monte Carlo simulations about adsorption, pore size distribution and accessible surface area reveal the capability of 2 for H2 purification applications.

PhotoluminescenceMaterials science010405 organic chemistryLigandInorganic chemistrychemistry.chemical_elementGeneral Chemistry010402 general chemistryCondensed Matter Physics01 natural sciencesHydrothermal circulation0104 chemical sciencesAccessible surface areaMetalAdsorptionchemistryvisual_artvisual_art.visual_art_mediumGeneral Materials ScienceMetal-organic frameworkCobaltCrystEngComm
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CCDC 1884201: Experimental Crystal Structure Determination

2020

Related Article: Amalia García-García, José M. Méndez-Arriaga, Rubén Martín-Escolano, Javier Cepeda, Santiago Gómez-Ruiz, Alfonso Salinas-Castillo, José M. Seco, Manuel Sánchez-Moreno, Duane Choquesillo-Lazarte, Ana B. Ruiz-Muelle, Ignacio Fernández, Clotilde Marín, Antonio Rodríguez-Diéguez|2020|Polyhedron|184|114570|doi:10.1016/j.poly.2020.114570

Space GroupCrystallographycatena-((mu-aqua)-diaqua-bis({2-[(26-dichlorophenyl)amino]phenyl}acetato)-manganese ethanol solvate)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1884200: Experimental Crystal Structure Determination

2020

Related Article: Amalia García-García, José M. Méndez-Arriaga, Rubén Martín-Escolano, Javier Cepeda, Santiago Gómez-Ruiz, Alfonso Salinas-Castillo, José M. Seco, Manuel Sánchez-Moreno, Duane Choquesillo-Lazarte, Ana B. Ruiz-Muelle, Ignacio Fernández, Clotilde Marín, Antonio Rodríguez-Diéguez|2020|Polyhedron|184|114570|doi:10.1016/j.poly.2020.114570

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-((mu-aqua)-diaqua-bis({2-[(26-dichlorophenyl)amino]phenyl}acetato)-nickel ethanol solvate)Experimental 3D Coordinates
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