0000000001309561

AUTHOR

Sheng-hong Li

showing 2 related works from this author

Abyssomicin E, a highly functionalized polycyclic metabolite from Streptomyces species.

2007

Abyssomicin E (1), a new polycyclic metabolite with a C19 skeleton, was isolated from Streptomyces sp. (HKI0381). Its chemical structure was determined by comprehensive NMR and MS spectroscopic analyses. For the first time in this recently discovered class of compounds, the absolute stereochemistry was directly established by subsequent single-crystal X-ray diffraction study using anomalous dispersion with copper radiation.

Models MolecularbiologyMolecular StructureChemistryStereochemistryChemical structureMetaboliteOrganic ChemistryGeneral MedicineAbyssomicin Ebiology.organism_classificationBridged Bicyclo Compounds HeterocyclicBiochemistryStreptomycesStreptomyces speciesStreptomyceschemistry.chemical_compoundOrganic chemistryPhysical and Theoretical ChemistryOrganic letters
researchProduct

CCDC 654035: Experimental Crystal Structure Determination

2007

Related Article: Xue-Mei Niu, Sheng-Hong Li, Helmar Gorls, D.Schollmeyer, M.Hilliger, S.Grabley, I.Sattler|2007|Org.Lett.|9|2437|doi:10.1021/ol0705999

Space GroupCrystallographyCrystal SystemCrystal Structure(2R3R4R4aS5R5aS7R9R12aR12bS)-4710-Trihydroxy-5-methoxy-279-trimethyl-12-oxo-12344a55a67891112a12b-tetradecahydrobenzo(g)cyclo-octa(cd)pentalene-611-dione methanol solvateCell ParametersExperimental 3D Coordinates
researchProduct