0000000001309825
AUTHOR
Ayla Päpcke
showing 10 related works from this author
Gold(II) Porphyrins in Photoinduced Electron Transfer Reactions
2019
Chemistry - a European journal 25(23), 5940 - 5949 (2019). doi:10.1002/chem.201900050
Green-Light Activation of Push-Pull Ruthenium(II) Complexes.
2020
Abstract Synthesis, characterization, electrochemistry, and photophysics of homo‐ and heteroleptic ruthenium(II) complexes [Ru(cpmp)2]2+ (22+) and [Ru(cpmp)(ddpd)]2+ (32+) bearing the tridentate ligands 6,2’’‐carboxypyridyl‐2,2’‐methylamine‐pyridyl‐pyridine (cpmp) and N,N’‐dimethyl‐N,N’‐dipyridin‐2‐ylpyridine‐2,6‐diamine (ddpd) are reported. The complexes possess one (32+) or two (22+) electron‐deficient dipyridyl ketone fragments as electron‐accepting sites enabling intraligand charge transfer (ILCT), ligand‐to‐ligand charge transfer (LL'CT) and low‐energy metal‐to‐ligand charge transfer (MLCT) absorptions. The latter peak around 544 nm (green light). Complex 22+ shows 3MLCT phosphorescenc…
Ground- and Excited-State Properties of Iron(II) Complexes Linked to Organic Chromophores
2020
Two new bichromophoric complexes, [Fe(bim-ant)2]2+ and [Fe(bim-pyr)2]2+ ([H2-bim]2+ = 1,1′-(pyridine-2,6-diyl)bis(3-methyl-1H-imidazol-3-ium); ant = 9-anthracenyl; pyr = 1-pyrenyl), are investigate...
Cover Feature: Excited‐State Kinetics of an Air‐Stable Cyclometalated Iron(II) Complex (Chem. Eur. J. 51/2019)
2019
A Vanadium(III) Complex with Blue and NIR-II Spin-Flip Luminescence in Solution.
2020
Luminescence from Earth-abundant metal ions in solution at room temperature is a very challenging objective due to the intrinsically weak ligand field splitting of first-row transition metal ions, which leads to efficient nonradiative deactivation via metal-centered states. Only a handful of 3d
Excited-State Kinetics of an Air-Stable Cyclometalated Iron(II) Complex.
2019
The complex class [Fe(N^N^C)(N^N^N)]+ with an Earth-abundant metal ion has been repeatedly suggested as a chromophore and potential photosensitizer on the basis of quantum chemical calculations. Synthesis and photophysical properties of the parent complex [Fe(pbpy)(tpy)]+ (Hpbpy=6-phenyl-2,2'-bipyridine and tpy=2,2':6',2''-terpyridine) of this new chromophore class are now reported. Ground-state characterization by X-ray diffraction, electrochemistry, spectroelectrochemistry, UV/Vis, and X-ray spectroscopy in combination with DFT calculations proves the high impact of the cyclometalating ligand on the electronic structure. The photophysical properties are significantly improved compared to …
Cover Feature: Green‐Light Activation of Push–Pull Ruthenium(II) Complexes (Chem. Eur. J. 30/2020)
2020
CCDC 1958562: Experimental Crystal Structure Determination
2020
Related Article: Matthias Dorn, Jens Kalmbach, Pit Boden, Ayla Päpcke, Sandra Gómez, Christoph Förster, Felix Kuczelinis, Luca M. Carrella, Laura A. Büldt, Nicolas H. Bings, Eva Rentschler, Stefan Lochbrunner, Leticia González, Markus Gerhards, Michael Seitz, Katja Heinze|2020|J.Am.Chem.Soc.|142|7947|doi:10.1021/jacs.0c02122
CCDC 1904835: Experimental Crystal Structure Determination
2020
Related Article: Jakob Steube, Lukas Burkhardt, Ayla Päpcke, Johannes Moll, Peter Zimmer, Roland Schoch, Christoph Wölper, Katja Heinze, Stefan Lochbrunner, Matthias Bauer|2019|Chem.-Eur.J.|25|11826|doi:10.1002/chem.201902488
CCDC 1852838: Experimental Crystal Structure Determination
2020
Related Article: Johannnes Moll, Cui Wang, Ayla Päpcke, Christoph Förster, Ute Resch-Genger, Stefan Lochbrunner, Katja Heinze|2020|Chem.-Eur.J.|26|6820|doi:10.1002/chem.202000871