6533b828fe1ef96bd1288438

RESEARCH PRODUCT

A Vanadium(III) Complex with Blue and NIR-II Spin-Flip Luminescence in Solution.

Christoph FörsterKatja HeinzeEva RentschlerNicolas H. BingsJens KalmbachPit BodenFelix KuczelinisStefan LochbrunnerLuca M. CarrellaLeticia GonzálezMatthias DornSandra GómezAyla PäpckeLaura A. BüldtMarkus GerhardsMichael Seitz

subject

Ligand field theoryChemistryMetal ions in aqueous solutionVanadiumchemistry.chemical_elementGeneral Chemistry010402 general chemistryPhotochemistry01 natural sciencesBiochemistryCatalysisTransition metal ions0104 chemical sciencesCondensed Matter::Materials ScienceColloid and Surface ChemistryPhysics::Plasma PhysicsSpin-flipLuminescence

description

Luminescence from Earth-abundant metal ions in solution at room temperature is a very challenging objective due to the intrinsically weak ligand field splitting of first-row transition metal ions, which leads to efficient nonradiative deactivation via metal-centered states. Only a handful of 3d

yearjournalcountryeditionlanguage
2020-04-11Journal of the American Chemical Society
10.1021/jacs.0c02122https://pubmed.ncbi.nlm.nih.gov/32275150