0000000001310801
AUTHOR
M.t. Albelda
Kinetic study of the oxidation of [Fe(CN)6]4− by [Co(NH3)4pzCO2]2+ and S2O82- in the presence of the tripodal ligand Tren Aminopropil
Abstract Oxidations (electron transfers) of [Fe(CN)6]4− by [Co(NH3)4pzCO2]2+ and S 2 O 8 2 - have been studied in solutions containing the receptor N,N′,N″-(aminopropil)-tris (2-aminoetil) amina [Tren Aminopropil, TAL], which can incorporate [Fe(CN)6]4− and S 2 O 8 2 - but not the cobalt complex. The results can be explained using the Bronsted equation that allows to obtain the binding constant of the transition state, a parameter that the Pseudophase Model cannot provide.
CCDC 897978: Experimental Crystal Structure Determination
Related Article: M.Inclan, M.T.Albelda, J.C.Frias, S.Blasco, B.Verdejo, C.Serena, C.Salat-Canela, M.L.Diaz, A.Garcia-Espana, E.Garcia-Espana|2012|J.Am.Chem.Soc.|134|9644|doi:10.1021/ja300538s
CCDC 897979: Experimental Crystal Structure Determination
Related Article: M.Inclan, M.T.Albelda, J.C.Frias, S.Blasco, B.Verdejo, C.Serena, C.Salat-Canela, M.L.Diaz, A.Garcia-Espana, E.Garcia-Espana|2012|J.Am.Chem.Soc.|134|9644|doi:10.1021/ja300538s