6533b859fe1ef96bd12b8027

RESEARCH PRODUCT

Kinetic study of the oxidation of [Fe(CN)6]4− by [Co(NH3)4pzCO2]2+ and S2O82- in the presence of the tripodal ligand Tren Aminopropil

Maria MarchenaM.t. AlbeldaEnrique García-españaAlejandra Sornosa-tenFrancisco Sánchez

subject

CrystallographychemistryComputational chemistryTripodal ligandGeneral Physics and Astronomychemistry.chemical_elementElectronPhysical and Theoretical ChemistryKinetic energyCobaltBinding constant

description

Abstract Oxidations (electron transfers) of [Fe(CN)6]4− by [Co(NH3)4pzCO2]2+ and S 2 O 8 2 - have been studied in solutions containing the receptor N,N′,N″-(aminopropil)-tris (2-aminoetil) amina [Tren Aminopropil, TAL], which can incorporate [Fe(CN)6]4− and S 2 O 8 2 - but not the cobalt complex. The results can be explained using the Bronsted equation that allows to obtain the binding constant of the transition state, a parameter that the Pseudophase Model cannot provide.

yearjournalcountryeditionlanguage
2011-03-01Chemical Physics Letters
https://doi.org/10.1016/j.cplett.2011.02.031