Author: Amgalanbaatar Baldansuren

0000000001311132

AUTHOR

Amgalanbaatar Baldansuren

Structural and electronic elucidation of a N-heterocyclic silylene vanadocene adduct

The solid and solution state structure of the vanadium(II) N‐ heterocyclic silylene (NHSi) complex, [(SiIPr)V(Cp)2] (1) is reported ( SiIPr: 1,3‐bis(2,6‐diisopropylphenyl)‐1,3‐diaza‐2‐silacyclopent‐4‐ en‐2‐ylidene). The electronic structure of 1 is probed using combination of magnetic measurements, EPR spectroscopy and computational studies. The V–Si bond strength and complex forming mechanism between vanadocene and NHSi ligand is elucidated using computational methods. peerReviewed

research product

CCDC 1485743: Experimental Crystal Structure Determination

Related Article: Mikko M. Hänninen, Amgalanbaatar Baldansuren, Thomas Pugh|2017|Dalton Trans.|46|9740|doi:10.1039/C7DT01226H

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