0000000001311724

AUTHOR

Tiina Saloranta

showing 2 related works from this author

From Mannose to Small Amphiphilic Polyol: Perfect Linearity Leads To Spontaneous Aggregation

2016

Terminally unsaturated and diastereochemically pure polyol derived from d-mannose shows spontaneous aggregation behavior in water solution. In order to study and clarify this unforeseen phenomenon, a conformational study based on NMR spectroscopy combined with ab initio structure analysis using the COSMO-solvation model was pursued. The results, together with X-ray diffraction studies, suggest a low energy linear conformation for this particular substrate both in solid states and in solution. For such small-sized acyclic carbohydrate derivatives, the linear conformation appears to be a key prerequisite for the unusual molecular self-assembly reported herein. peerReviewed

X ray diffractionAb initioMannosed-mannose010402 general chemistry01 natural sciencesspontaneous aggregationchemistry.chemical_compoundPolyolAmphiphileGeneral Materials Scienceta116Nuclear magnetic resonance spectroscopychemistry.chemical_classificationpolyolsta114010405 organic chemistryChemistrySubstrate (chemistry)General ChemistryNuclear magnetic resonance spectroscopySelf assemblyCondensed Matter Physics0104 chemical sciencesCrystallographyX-ray crystallographySelf-assemblyCrystal Growth & Design
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CCDC 1406085: Experimental Crystal Structure Determination

2016

Related Article: Tiina Saloranta, Anssi Peuronen, Johannes M. Dieterich, Janne Ruokolainen, Manu Lahtinen, Reko Leino|2016|Cryst.Growth Des.|16|655|doi:10.1021/acs.cgd.5b01135

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersnon-8-ene-123456-hexolExperimental 3D Coordinates
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