Characterization of Flux-Grown SmxNd1–xVO4 Compounds and High-Pressure Behavior for x = 0.5

The crystal structure and the vibrational and optical characteristics of flux-grown mixed lanthanide vanadate compounds SmxNd1–xVO4 (x = 0, 0.1, 0.25, 0.5, 0.75 and 1) are reported. A linear, monot...

Magnetic Properties of a New Hexahalorhenate(IV) Compound and Structural Comparison with Its Hexahaloplatinate(IV) Analog

Compressibility Systematics of Calcite-Type Borates: An Experimental and Theoretical Structural Study on ABO(3) (A = Al, Sc, Fe, and In)

The structural properties of calcite-type orthoborates ABO(3) (A = Al, Fe, Sc, and In) have been investigated at high pressures up to 32 GPa. They were studied experimentally using synchrotron powder X-ray diffraction and theoretically by means of ab initio total-energy calculations. We found that the calcite-type structure remains stable up to the highest pressure explored in the four studied compounds. Experimental and calculated static geometries (unit-cell parameters and internal coordinates), bulk moduli, and their pressure derivatives are in good agreement. The compressibility along the c axis is roughly three times that along the a axis. Our data clearly indicate that the compressibi…

CCDC 1983533: Experimental Crystal Structure Determination

Related Article: Fabio Piccinelli, Marco Bettinelli, Joan Cano, Francesc Lloret, Miguel Julve, Alessandro Dolmella|2020|Eur.J.Inorg.Chem.|2020|2246|doi:10.1002/ejic.202000199

CCDC 1983534: Experimental Crystal Structure Determination

Related Article: Fabio Piccinelli, Marco Bettinelli, Joan Cano, Francesc Lloret, Miguel Julve, Alessandro Dolmella|2020|Eur.J.Inorg.Chem.|2020|2246|doi:10.1002/ejic.202000199