0000000001313124
AUTHOR
Céline Besnard
Very Long-Lived Photogenerated High-Spin Phase of a Multistable Spin-Crossover Molecular Material
The spin-crossover compound [Fe(n-Bu-im)3(tren)](PF6)2 shows an unusual long relaxation time of 20 h after light-induced excited spin state trapping when irradiating at 80 K. This is more than 40 times longer than when irradiating at 10 K. Optical absorption spectroscopy, magnetometry, and X-ray diffraction using synchrotron radiation were used to characterize and explain the different relaxation behaviors of this compound after irradiation below and above 70 K. Rearrangement of the butyl chains of the ligands occurring during the relaxation after irradiation above 70 K is thought to be responsible for the unusually long relaxation time at this temperature.
CCDC 1848631: Experimental Crystal Structure Determination
Related Article: Teresa Delgado, Antoine Tissot, Laure Guénée, Andreas Hauser, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, José Antonio Real, Sébastien Pillet, El-Eulmi Bendeif, Céline Besnard|2018|J.Am.Chem.Soc.|140|12870|doi:10.1021/jacs.8b06042
CCDC 1848628: Experimental Crystal Structure Determination
Related Article: Teresa Delgado, Antoine Tissot, Laure Guénée, Andreas Hauser, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, José Antonio Real, Sébastien Pillet, El-Eulmi Bendeif, Céline Besnard|2018|J.Am.Chem.Soc.|140|12870|doi:10.1021/jacs.8b06042
CCDC 1857201: Experimental Crystal Structure Determination
Related Article: Teresa Delgado, Antoine Tissot, Laure Guénée, Andreas Hauser, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, José Antonio Real, Sébastien Pillet, El-Eulmi Bendeif, Céline Besnard|2018|J.Am.Chem.Soc.|140|12870|doi:10.1021/jacs.8b06042
CCDC 1848626: Experimental Crystal Structure Determination
Related Article: Teresa Delgado, Antoine Tissot, Laure Guénée, Andreas Hauser, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, José Antonio Real, Sébastien Pillet, El-Eulmi Bendeif, Céline Besnard|2018|J.Am.Chem.Soc.|140|12870|doi:10.1021/jacs.8b06042
CCDC 1848629: Experimental Crystal Structure Determination
Related Article: Teresa Delgado, Antoine Tissot, Laure Guénée, Andreas Hauser, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, José Antonio Real, Sébastien Pillet, El-Eulmi Bendeif, Céline Besnard|2018|J.Am.Chem.Soc.|140|12870|doi:10.1021/jacs.8b06042
CCDC 1848627: Experimental Crystal Structure Determination
Related Article: Teresa Delgado, Antoine Tissot, Laure Guénée, Andreas Hauser, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, José Antonio Real, Sébastien Pillet, El-Eulmi Bendeif, Céline Besnard|2018|J.Am.Chem.Soc.|140|12870|doi:10.1021/jacs.8b06042