Author: Rubén Sánchez-garcía

0000000001313135

AUTHOR

Rubén Sánchez-garcía

showing 3 related works from this author

Enantioselective Synthesis of 2-Amino-1,1-diarylalkanes Bearing a Carbocyclic Ring Substituted Indole through Asymmetric Catalytic Reaction of Hydrox…

2018

[EN] An asymmetric catalytic reaction of hydroxyindoles with nitroalkenes leading to the Friedel-Crafts alkylation in the carbocyclic ring of indole is presented. The method is based on the activating/directing effects of the hydroxy group situated in the carbocyclic ring of the indole providing nitroalkylated indoles functionalizated at the C-4, C-5, and C-7 positions with high yield, regio-, and enantioselectivity. The optically enriched nitroalkanes were transformed efficiently in optically enriched 2-amino-1,1-diarylalkanes bearing a carbocyclic ring substituted indole.

Indole test010405 organic chemistryChemistryStereochemistryOrganic ChemistryHydroxy groupEnantioselective synthesisAlkylation010402 general chemistryRing (chemistry)01 natural sciencesReaccions químiques0104 chemical sciencesCatalysischemistry.chemical_compoundCatàlisiFISICA APLICADAYield (chemistry)Química orgànicaThe Journal of Organic Chemistry

researchProduct

CCDC 1821100: Experimental Crystal Structure Determination

2018

Related Article: Carlos Vila, Jaume Rostoll-Berenguer, Rubén Sánchez-García, Gonzalo Blay, Isabel Fernández, M. Carmen Muñoz, and José R. Pedro|2018|J.Org.Chem.|83|6397|doi:10.1021/acs.joc.8b00612

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates7-[1-(4-bromophenyl)-2-nitroethyl]-1H-indol-6-ol

researchProduct

CCDC 1821099: Experimental Crystal Structure Determination

2018

Related Article: Carlos Vila, Jaume Rostoll-Berenguer, Rubén Sánchez-García, Gonzalo Blay, Isabel Fernández, M. Carmen Muñoz, and José R. Pedro|2018|J.Org.Chem.|83|6397|doi:10.1021/acs.joc.8b00612

5-[1-(4-bromophenyl)-2-nitroethyl]-1H-indol-4-olSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

PEPhysical Sciences and Engineering
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