0000000001313373

AUTHOR

María Vicent-morales

showing 2 related works from this author

Semiconductor Porous Hydrogen-Bonded Organic Frameworks Based on Tetrathiafulvalene Derivatives.

2022

Herein, we report on the use of tetrathiavulvalene-tetrabenzoic acid, H4TTFTB, to engender semiconductivity in porous hydrogen-bonded organic frameworks (HOFs). By tuning the synthetic conditions, three different polymorphs have been obtained, denoted MUV-20a, MUV-20b, and MUV-21, all of them presenting open structures (22, 15, and 27%, respectively) and suitable TTF stacking for efficient orbital overlap. Whereas MUV-21 collapses during the activation process, MUV-20a and MUV-20b offer high stability evacuation, with a CO2 sorption capacity of 1.91 and 1.71 mmol g-1, respectively, at 10 °C and 6 bar. Interestingly, both MUV-20a and MUV-20b present a zwitterionic character with a positively…

Colloid and Surface ChemistryGeneral ChemistryCristallsConductivitat elèctricaBiochemistryCatalysisJournal of the American Chemical Society
researchProduct

CCDC 1897432: Experimental Crystal Structure Determination

2019

Related Article: María Vicent-Morales, Iñigo J. Vitórica-Yrezábal, Manuel Souto, Guillermo Mínguez Espallargas|2019|CrystEngComm|21|3031|doi:10.1039/C9CE00233B

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[tris(mu-2367-tetrakis(4-carboxylatophenyl)tetrathiafulvalene)-bis(mu-oxo)-hexapyridine-hexa-iron pyridine solvate]Cell ParametersExperimental 3D Coordinates
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