Author: Amelle Mankou-makaya

0000000001313923

AUTHOR

Amelle Mankou-makaya

Regioselective C–H amination of free base porphyrins via electrogenerated pyridinium-porphyrins and stabilization of easily oxidized amino-porphyrins by protonation

Four free base aminoporphyrins were synthesized in two steps via regioselective anodic nucleophilic substitution with pyridine followed by ring opening of the electrogenerated pyridinium with piperidine. The X-ray crystallographic structure of the unstable 2-aminotetraphenylporphyrin was solved. Protonation of this latter compound leads to the stable diiminium porphyrin salt.

research product

CCDC 1952439: Experimental Crystal Structure Determination

Related Article: Asmae Bousfiha, Abdou K. D. Dimé, Amelle Mankou-Makaya, Julie Echaubard, Mathieu Berthelot, Hélène Cattey, Anthony Romieu, Julien Roger, Charles H. Devillers|2020|Chem.Commun.|56|884|doi:10.1039/C9CC07351E

research product

CCDC 1952440: Experimental Crystal Structure Determination

Related Article: Asmae Bousfiha, Abdou K. D. Dimé, Amelle Mankou-Makaya, Julie Echaubard, Mathieu Berthelot, Hélène Cattey, Anthony Romieu, Julien Roger, Charles H. Devillers|2020|Chem.Commun.|56|884|doi:10.1039/C9CC07351E

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PEPhysical Sciences and Engineering
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