0000000001313975

AUTHOR

Qinliang Zhao

showing 3 related works from this author

High Yield Syntheses of Stable, Singly Bonded Pd26+ Compounds

2006

A general method for the syntheses of dipalladium compounds having a singly bonded Pd26+ core and the formula R,S-cis-Pd2(C6H4PPh2)2(O2CR)2Cl2 is described. When the alkyl group in the carboxylate ligands is an electron donating group, the compounds are stable and the yields high. The Pd-Pd distances for the diamagnetic compounds with R = CF3 and CMe3 are 2.5434(4) and 2.5241(9) A, respectively. Calculations at the DFT level suggest that the electronic configuration is sigma2pi4delta2delta*2pi*4. These represent rare examples of palladium(III) compounds.

chemistry.chemical_classificationGeneral methodStereochemistrychemistry.chemical_elementGeneral ChemistryBiochemistryMedicinal chemistryCatalysischemistry.chemical_compoundColloid and Surface ChemistrychemistryGroup (periodic table)Yield (chemistry)DiamagnetismCarboxylateElectron configurationAlkylPalladiumJournal of the American Chemical Society
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CCDC 628883: Experimental Crystal Structure Determination

2007

Related Article: Francisco Estevan, Pipsa Hirva, Mercedes Sanaú, MaAngeles Úbeda|2018|Organometallics|37|2980|doi:10.1021/acs.organomet.8b00342

cis-bis(mu~2~-2-(Diphenylphosphino)phenyl)-bis(mu~2~-pivalato)-dichloro-di-palladium(ii)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 628882: Experimental Crystal Structure Determination

2007

Related Article: Francisco Estevan, Pipsa Hirva, Mercedes Sanaú, MaAngeles Úbeda|2018|Organometallics|37|2980|doi:10.1021/acs.organomet.8b00342

Space GroupCrystallographycis-bis(mu~2~-2-(Diphenylphosphino)phenyl)-bis(mu~2~-trifluoroacetato)-dichloro-di-palladium(ii) dichloromethane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct