High Yield Syntheses of Stable, Singly Bonded Pd26+ Compounds

6533b85ffe1ef96bd12c263c

RESEARCH PRODUCT

High Yield Syntheses of Stable, Singly Bonded Pd26+ Compounds

Qinliang Zhao Igor O. Koshevoy Mercedes Sanaú M. Angeles Ubeda F. Albert Cotton Carlos A. Murillo Pascual Lahuerta

subject

chemistry.chemical_classification General method Stereochemistry chemistry.chemical_element General Chemistry Biochemistry Medicinal chemistry Catalysis chemistry.chemical_compound Colloid and Surface Chemistry chemistry Group (periodic table)Yield (chemistry)Diamagnetism Carboxylate Electron configuration Alkyl Palladium

description

A general method for the syntheses of dipalladium compounds having a singly bonded Pd26+ core and the formula R,S-cis-Pd2(C6H4PPh2)2(O2CR)2Cl2 is described. When the alkyl group in the carboxylate ligands is an electron donating group, the compounds are stable and the yields high. The Pd-Pd distances for the diamagnetic compounds with R = CF3 and CMe3 are 2.5434(4) and 2.5241(9) A, respectively. Calculations at the DFT level suggest that the electronic configuration is sigma2pi4delta2delta*2pi*4. These represent rare examples of palladium(III) compounds.

year	journal	country	edition	language
2006-10-19	Journal of the American Chemical Society

https://doi.org/10.1021/ja0656595

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