0000000001314156

AUTHOR

ÉRica Neves De Faria

showing 5 related works from this author

A heterobimetallic [MnII5CuII5] nanowheel modulated by a flexible bis-oxamate type ligand

2015

The synthesis, crystal structure and preliminary magnetic characterization of a new heterobimetallic [MnII5CuII5] wheel containing a flexible bis-oxamate type ligand are described. This decanuclear compound exhibits a relatively strong intra-wheel antiferromagnetic interaction leading to a ground spin state S = 10.

Inorganic ChemistrySpin statesLigandChemistryStereochemistryAntiferromagnetismCrystal structureType (model theory)Dalton Transactions
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Solvent effects on the dimensionality of oxamato-bridged manganese(II) compounds

2018

Two new oxamate-containing manganese(II) complexes, [{Mn(H2edpba)(H2O)2}2]n (1) and [Mn(H2edpba)(dmso)2]∙dmso∙CH3COCH3∙H2O (2) (H4edpba = N,N′-ethylenediphenylenebis(oxamic acid) and dmso = dimethylsulfoxide), have been synthesized and the structures of 1 and 2 were characterized by single crystal X-ray diffraction. The structure of 1 consists of neutral honeycomb networks in which each manganese(II) is six-coordinate by one H2edpba2− ligand and two carboxylate–oxygens from two other H2edpba2− ligands building the equatorial plane. Each manganese is connected to its nearest neighbor through two carboxylate(monoprotonated oxamate) bridges in an anti-syn conformation. A dmso solution of singl…

010405 organic chemistryLigandSupramolecular chemistrychemistry.chemical_elementManganese010402 general chemistry01 natural sciences0104 chemical scienceschemistry.chemical_compoundCrystallographychemistryX-ray crystallographyMaterials ChemistryMoleculeCarboxylatePhysical and Theoretical ChemistrySolvent effectsSingle crystal
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A pH-triggered bistable copper(II) metallacycle as a reversible emulsion switch for biphasic processes.

2013

A unique bistable copper-metallacyclic complex is used as an elegant molecular switch for the reversible formation of emulsions by simple pH variation. This switch may have several exciting applications in biphasic processes such as catalysis and separation science technologies.

Molecular switchBistabilityChemistryMetals and Alloyschemistry.chemical_elementGeneral ChemistryMetallacyclePhotochemistryCopperCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCatalysisEmulsionMaterials ChemistryCeramics and CompositesPh triggeredChemical communications (Cambridge, England)
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CCDC 1580311: Experimental Crystal Structure Determination

2018

Related Article: Julia Parreiras de Matos, Érica Neves de Faria, Willian Xerxes Coelho Oliveira, Walace Doti do Pim, Raquel Vieira Mambrini, Emerson Fernandes Pedroso, Miguel Julve, Cynthia Lopes Martins Pereira, Humberto Osório Stumpf|2018|J.Coord.Chem.|71|797|doi:10.1080/00958972.2018.1439162

Space GroupCrystallography[22'-{ethane-12-diylbis[(21-phenylene)azanediyl]}bis[(oxo)acetato]]-bis[dimethyl sulfoxide]-manganese(ii) dimethyl sulfoxide acetone solvate monohydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1580310: Experimental Crystal Structure Determination

2018

Related Article: Julia Parreiras de Matos, Érica Neves de Faria, Willian Xerxes Coelho Oliveira, Walace Doti do Pim, Raquel Vieira Mambrini, Emerson Fernandes Pedroso, Miguel Julve, Cynthia Lopes Martins Pereira, Humberto Osório Stumpf|2018|J.Coord.Chem.|71|797|doi:10.1080/00958972.2018.1439162

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[(mu-22'-{ethane-12-diylbis[(21-phenylene)azanediyl]}bis(oxoacetato))-diaqua-manganese(ii)]Experimental 3D Coordinates
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