0000000001314156
AUTHOR
ÉRica Neves De Faria
A heterobimetallic [MnII5CuII5] nanowheel modulated by a flexible bis-oxamate type ligand
The synthesis, crystal structure and preliminary magnetic characterization of a new heterobimetallic [MnII5CuII5] wheel containing a flexible bis-oxamate type ligand are described. This decanuclear compound exhibits a relatively strong intra-wheel antiferromagnetic interaction leading to a ground spin state S = 10.
Solvent effects on the dimensionality of oxamato-bridged manganese(II) compounds
Two new oxamate-containing manganese(II) complexes, [{Mn(H2edpba)(H2O)2}2]n (1) and [Mn(H2edpba)(dmso)2]∙dmso∙CH3COCH3∙H2O (2) (H4edpba = N,N′-ethylenediphenylenebis(oxamic acid) and dmso = dimethylsulfoxide), have been synthesized and the structures of 1 and 2 were characterized by single crystal X-ray diffraction. The structure of 1 consists of neutral honeycomb networks in which each manganese(II) is six-coordinate by one H2edpba2− ligand and two carboxylate–oxygens from two other H2edpba2− ligands building the equatorial plane. Each manganese is connected to its nearest neighbor through two carboxylate(monoprotonated oxamate) bridges in an anti-syn conformation. A dmso solution of singl…
A pH-triggered bistable copper(II) metallacycle as a reversible emulsion switch for biphasic processes.
A unique bistable copper-metallacyclic complex is used as an elegant molecular switch for the reversible formation of emulsions by simple pH variation. This switch may have several exciting applications in biphasic processes such as catalysis and separation science technologies.
CCDC 1580311: Experimental Crystal Structure Determination
Related Article: Julia Parreiras de Matos, Érica Neves de Faria, Willian Xerxes Coelho Oliveira, Walace Doti do Pim, Raquel Vieira Mambrini, Emerson Fernandes Pedroso, Miguel Julve, Cynthia Lopes Martins Pereira, Humberto Osório Stumpf|2018|J.Coord.Chem.|71|797|doi:10.1080/00958972.2018.1439162
CCDC 1580310: Experimental Crystal Structure Determination
Related Article: Julia Parreiras de Matos, Érica Neves de Faria, Willian Xerxes Coelho Oliveira, Walace Doti do Pim, Raquel Vieira Mambrini, Emerson Fernandes Pedroso, Miguel Julve, Cynthia Lopes Martins Pereira, Humberto Osório Stumpf|2018|J.Coord.Chem.|71|797|doi:10.1080/00958972.2018.1439162