6533b7dcfe1ef96bd12727c2

RESEARCH PRODUCT

A heterobimetallic [MnII5CuII5] nanowheel modulated by a flexible bis-oxamate type ligand

Humberto O. StumpfCynthia L. M. PereiraJoan CanoCarlos B. PinheiroMiguel JulveWillian X. C. OliveiraWalace D. Do PimWalace D. Do PimFrancesc LloretWallace C. NunesÉRica Neves De Faria

subject

Inorganic ChemistrySpin statesLigandChemistryStereochemistryAntiferromagnetismCrystal structureType (model theory)

description

The synthesis, crystal structure and preliminary magnetic characterization of a new heterobimetallic [MnII5CuII5] wheel containing a flexible bis-oxamate type ligand are described. This decanuclear compound exhibits a relatively strong intra-wheel antiferromagnetic interaction leading to a ground spin state S = 10.

https://doi.org/10.1039/c5dt00996k