0000000000297180
AUTHOR
Carlos B. Pinheiro
Crystal Engineering Applied to Modulate the Structure and Magnetic Properties of Oxamate Complexes Containing the [Cu(bpca)]+ Cation
This work deals with the crystal engineering features of four related copper(II)-based compounds with formulas {[{Cu(bpca)}2(H2ppba)]·1.33DMF·0.66DMSO}n (2), [{Cu(bpca)(H2O)}2(H2ppba)] (3), [{Cu(bpca)}2(H2ppba)]·DMSO (4), and [{Cu(bpca)}2(H2ppba)]·6H2O (5) [H4ppba = N,N′-1,4-phenylenebis(oxamic acid) and Hbpca = bis(2-pyridylcarbonyl)amide] and how their distinct molecular and crystal structures translate into their different magnetic properties. 2 and 3 were obtained through the hydrolytic reaction of the double-stranded oxamato-based dipalladium(II) paracyclophane precursor of formula [{K4(H2O)2}{Pd2(ppba)2}] (1) with the mononuclear copper(II) complex [Cu(bpca)(H2O)2]+, either in a water…
A two-dimensional oxamate- and oxalate-bridged Cu(II)Mn(II) motif: crystal structure and magnetic properties of (Bu4N)2[Mn2{Cu(opba)}2ox].
A new compound of formula (Bu4N)2[Mn2{Cu(opba)}2ox] (1) [Bu4N(+) = tetra-n-butylammonium cation, H4opba = 1,2-phenylenebis(oxamic acid), and H2ox = oxalic acid] has been synthesized and magneto-structurally investigated. The reaction of manganese(II) acetate, [Cu(opba)](2-), and ox(2-) in dimethyl sulfoxide yielded single crystals of 1. The structure of 1 consists of heterobimetallic oxamato-bridged Cu(II)Mn(II) chains which are connected through bis-bidentate oxalate coordinated to the manganese(II) ions to afford anionic heterobimetallic layers of 6(3)-hcb net topology. The layers are interleaved by n-Bu4N(+) counterions. Each copper(II) ion in 1 is four-coordinate in a square planar envi…
Towards oxalate-bridged iron(ii), cobalt(ii), nickel(ii) and zinc(ii) complexes through oxotris(oxalato)niobate(v): an open air non-oxidizing synthetic route
Four compounds with the formula [M2(dmphen)4(μ-C2O4)](ClO4)2·2dmso [M = Fe (1), Co (2) and Zn (4); dmphen = 2,9-dimethyl-1,10-phenanthroline] and [Ni2(dmphen)4(μ-C2O4)]3[NbO(C2O4)3]2·16H2O (3) have been synthesized using the tris(oxalato)oxoniobate(V) complex anion as the oxalate source, and their structures have been determined by single crystal X-ray diffraction. X-ray quality crystals of highly insoluble oxalate-bridged species were obtained by taking advantage of the slow release of oxalate by the tris(oxalato)oxoniobate(V) complex anion. The structures of 1–4 all contain oxalate-bridged dimetal(II) units with didentate dmphen molecules acting as end-cap ligands; electroneutrality is ac…
Relatively strong intramolecular antiferromagnetic coupling in a neutral Cr(III)2Nb(V)2 heterobimetallic molecular square.
A relatively large antiferromagnetic interaction between the two chromium(III) ions from the molecular square [{Cr(dmso)4}2{Nb(μ-O)2(C2O4)2}2] () (J = -12.0 cm(-1)) is mediated by the diamagnetic oxo-Nb(V)-oxo pathway, its nature and magnitude being substantiated by DFT type theoretical calculations.
A heterobimetallic [MnII5CuII5] nanowheel modulated by a flexible bis-oxamate type ligand
The synthesis, crystal structure and preliminary magnetic characterization of a new heterobimetallic [MnII5CuII5] wheel containing a flexible bis-oxamate type ligand are described. This decanuclear compound exhibits a relatively strong intra-wheel antiferromagnetic interaction leading to a ground spin state S = 10.
Monitoring the hydrogen bond net configuration and the dimensionality of aniline and phenyloxamate by adding 1 H -pyrazole and isoxazole as substituents for molecular self-recognition
This work describes the synthesis and characterization of a new class of oxamic acid derivatives containing pyrazole and isoxazole as substituents to investigate their ability to form hydrogen bonds aiming at applying them in crystal engineering and molecular self-recognition. In this respect, we report a new synthesis of 2-(4-nitrophenyl)-1,3-propanedial (1) in high yield using SOCl2 as a chlorinating agent. The new oxamic esters 4-(1H-pyrazol-4-yl)phenylene-N-(ethyloxamate) (2d) and 4-(1,2-oxazol-4-yl)phenylene-N-(ethyloxamate) (3d) were prepared from 1. The synthetic route consists of the cyclisation of 1 either with hydrazine to afford 4-(-aminophenyl)-1H-pyrazole (2a) or with hydroxyla…
Crystal Structure and Magnetic Properties of an Oxamato‐Bridged Heterobimetallic Tetranuclear [Ni II Cu II ] 2 Complex of the Rack Type
Palladium(II)–Copper(II) Assembling with Bis(2-pyridylcarbonyl)amidate and Bis(oxamate) Type Ligands
Five new complexes of formula K4[Pd2(mpba)2] · 4H2O (1), {[K4(H2O)(dmso)][Pd2(mpba)2]} (2), {[Cu(bpca)]4[Pd2(mpba)2]} · 6H2O (3), {[Cu(bpca)]2[Pd(opba)]} · 1.75dmso · 0.25H2O (4), {[Cu(bpca)]2[Pd(opba)]}n · ndmso (5) [H4mpba =1,3-phenylenebis(oxamic acid), H4opba = 1,2-phenylenebis(oxamic acid), Hbpca = bis(2-pyridylcarbonyl)amide, and dmso = dimethyl sulfoxide] have been prepared and investigated by infrared spectroscopy, thermal analysis, single crystal X-ray diffraction, and magnetic susceptibility techniques. The structure of 2 consists of a [Pd2(mpba)2]4– anionic entity in which the palladium(II) cations are coordinated by two mpba ligands resulting in a dipalladium(II) unit that acts …
Copper(II) assembling with bis(2-pyridylcarbonyl)amidate and N,N'-2,2-phenylenebis(oxamate).
We herein present the synthesis and X-ray structures of five copper(II) complexes of formulae [Cu(bpca)(CF3SO3)(H2O)]·H2O (1), [Cu(bpca)(Phpr)(H2O)]·3/2H2O (2), {[Cu(bpca)]2[Cu(opba)(H2O)]}·H2O (3), {[Cu(bpca)]2(H2opba)}2·6H2O (4) and [Cu(bpca)(EtH2opba)]n (5), where bpca = bis(2-pyridylcarbonyl)amidate, Phpr = 3-phenylpropionate, CF3SO3(−) = triflate (anion of the trifluoromethanesulphonic acid), H4opba = N,N′-1,2-phenylenebis(oxamic acid), and EtH3opba = monoethyl ester derivative of the H4opba. 1 and 2 are mononuclear copper(II) complexes where the copper atom is five-coordinate in distorted square pyramidal surroundings with a tridentate bpca and a water molecule (1)/carboxylate oxygen …
Oxotris(oxalato)niobate(V) as counterion in cobalt(II) spin-crossover systems
Abstract This work is devoted to the investigation of the thermally induced spin-crossover behavior from a high-spin state (HS, S = 3/2) at higher temperatures to a low-spin phase (LS, S = 1/2) at lower temperatures of the six-coordinate cobalt(II) complex in the compound [Co(terpy)2]3[NbO(C2O4)3]2·3CH3OH·4H2O (2). The crystal structure of 2 together with that of its counterion as tetraphenylarsonium(V) salt (AsPh4)3[NbO(C2O4)3]·9H2O (1) are also included. The spin-crossover process was followed by the thermal variation of the χMT product between 2.0 and 400 K under the warming mode, with the LS configuration being achieved at T ⩽ 200 K and the LS → HS interconversion being incomplete at 4…
Oxotris(oxalate)niobate(V): An oxalate delivery agent in the design of building blocks
This work concerns the oxalate delivery process that occurs when using (NH4)3[NbO(C2O4)3]·6H2O as a suitable oxalate source in the synthesis of two compounds, [Cu(dmphen)(C2O4)(H2O)] (1) and [{Cu(dmphen)(CH3OH)}2(μ-C2O4)](ClO4)2 (2) (dmphen = 2,9-dimethyl-1,10-phenanthroline). {[Fe{HB(pz)3}(CN)2(μ-CN)]2[{Cu(dmphen)}2(μ-C2O4)]}∙xCH3OH (3) (2.0 ≤ x ≤ 2.4) was obtained by reacting 2 and PPh4[Fe{HB(pz)3}(CN)3]∙H2O [ = tetraphenylphosphonium and = tris(pyrazolyl)borate]. Crystal structures of 1–3 have been determined by single-crystal X-ray diffraction experiments: 1 is a mononuclear trigonal bipyramidal copper(II) species, 2 is a centrosymmetric oxalato-bridged dicopper(II) complex, and 3 consi…
Solvent-driven dimensionality control in molecular systems containing CuII, 2,2′-bipyridine and an oxamato-based ligand
A discrete dicopper(II) system, [Cu(bipy)(H2mpba)]2·2H2O (1), and its isomeric chain, [Cu(bipy)(H2mpba)]·dmso (2) [bipy = 2,2′-bipyridine and H4mpba = N,N′-1,3-phenylenebis(oxamic acid)], were obtained by modifying the ratio of the H2O–dmso solvent mixture, and their interconversion was also monitored by changing the solvents during the synthesis. The solvents play an essential role in the formation and crystallization of these complexes, presenting different dimensionalities and connectivities. The double deprotonated H2mpba2− adopts the bidentate/monodentate (1) and bis-bidentate (2) bridging modes toward the (2,2′-bipyridyl)copper(II) units affording a dinuclear compound (1) and a linear…
Unexpected formation of a dodecanuclear {CoII6CuII6} nanowheel under ambient conditions: magneto-structural correlations.
We report the unique heterobimetallic dodecanuclear oxamate-based {CoII6CuII6} nanowheel obtained using an environmentally friendly synthetic protocol. The effective Hamiltonian methodology employed herein allows the rationalisation of magnetic isotropic or anisotropic metal clusters, being a significant advance for future studies of exciting properties only observed at low and ultralow temperatures.
Influence of Copper(II) and Nickel(II) Ions in the Topology of Systems Based on a Flexible Bis-Oxamate and Bipyridine Building Blocks
Single crystals of the mononuclear bis-oxamate nickel(II) complex [Ni(bipy)(H2edpba)]·dmso (1) are obtained by reacting [Ni(bipy)Cl2]·H2O and the flexible K2(H2edpba) ligand [bipy = 2,2′-bipyridine; H4edpba = N,N′-2,2′-ethylenediphenylenebis(oxamic acid)]. The reaction of 1 with copper(II) ions resulted in two products in which the replacement of the nickel(II) ion by copper(II) took place: the chain compound [Cu(bipy)(H2edpba)]n·3nH2O·ndmso [dmso = dimethyl sulfoxide] (2) and the analogous chain compound without dmso crystallization molecules [Cu(bipy)(H2edpba)]n·1.5nH2O (3a) in its polycrystalline form. The reaction of [Cu(bipy)Cl2] and K2(H2edpba) yielded single crystals of [Cu(bipy)(H2e…
A pH-triggered bistable copper(II) metallacycle as a reversible emulsion switch for biphasic processes.
A unique bistable copper-metallacyclic complex is used as an elegant molecular switch for the reversible formation of emulsions by simple pH variation. This switch may have several exciting applications in biphasic processes such as catalysis and separation science technologies.
Magneto‐Structural Study of an Oxamato‐Bridged Pd II Co II Chain: X‐ray Crystallographic Evidence of a Single‐Crystal‐to‐Single‐Crystal Phase Transition
Two new mononuclear oxamato-containing palladium(II) complexes of formula K2[Pd(opba)]·2H2O (1) and (PPh4)2[Pd(opba)]·2H2O (2) and the heterodimetallic palladium(II)–cobalt(II) chain {[Co(H2O)2Pd(opba)]·dmso}n (3) [opba = 1,2-phenylenebis(oxamate), PPh4+ = tetraphenylphosphonium cation and dmso = dimethyl sulfoxide] have been prepared, and the structures of two of them (compounds 2 and 3) were determined by X-ray diffraction analysis of single crystals. The structure of 2 consists of discrete anions of [Pd(opba)2]2– and PPh4+ cations. Each PdII ion in 2 is surrounded by two oxamate nitrogen atoms and two carboxylate oxygen atoms in a square-planar surrounding. Compound 3 is a neutral chain …
Magneto-structural versatility of copper(II)-3-phenylpropionate coordination polymers with N-donor coligands.
A novel series of copper(II) coordination polymers [Cu2(O2CC8H9)4(pyz)]n (1), [Cu2(O2CC8H9)4(dps)]n (2), {[Cu(O2CC8H9)2(dps)(H2O)]·H2O}n (3), {[NaCu(O2CC8H9)2(bpm)(NO3)]·H2O}n (4), and [Cu4(O2CC8H9)6(OH)2(bpp)2]n (5) [O2CC8H9− = 3-phenylpropionate anion, pyz = pyrazine, dps = di(4-pyridyl)sulfide, bpm = 2,2′-bipyrimidine, and bpp = 1,3-bis(4-pyridyl)propane] have been synthesized and magneto-structurally investigated. Compounds 1 and 2 belong to a large group of copper(II) carboxylates where bis-monodentate pyz (1) and dps (2) ligands connect the paddle-wheel [CuII2(μ-O2CC8H9)4] units leading to alternating copper(II) chains. The structure of 3 consists of uniform chains of trans-[CuII(O2CC…
CCDC 1016163: Experimental Crystal Structure Determination
Related Article: Walace D. do Pim, Tatiana R. G. Simões, Willian X. C. Oliveira, Isabella R. A. Fernandes, Carlos B. Pinheiro, Francesc Lloret, Miguel Julve, Humberto O. Stumpf, Cynthia L. M. Pereira|2014|Cryst.Growth Des.|14|5929|doi:10.1021/cg501134y
CCDC 1469224: Experimental Crystal Structure Determination
Related Article: Willian X. C. Oliveira, Carlos B. Pinheiro, Marinez M. da Costa, Ana P. S. Fontes, Wallace C. Nunes, Francesc Lloret, Miguel Julve, Cynthia L. M. Pereira|2016|Cryst.Growth Des.|16|4094|doi:10.1021/acs.cgd.6b00613
CCDC 1818142: Experimental Crystal Structure Determination
Related Article: Willian X. C. Oliveira, Cynthia L. M. Pereira, Carlos B. Pinheiro, Francesc Lloret, Miguel Julve|2018|Inorg.Chem.Front.|5|1294|doi:10.1039/c8qi00191j
CCDC 1034456: Experimental Crystal Structure Determination
Related Article: Willian X. C. Oliveira, Marcos A. Ribeiro, Carlos B. Pinheiro, Marinez M. da Costa, Ana Paula S. Fontes, Wallace C. Nunes, Danielle Cangussu, Miguel Julve, Humberto O. Stumpf, Cynthia L. M. Pereira|2015|Cryst.Growth Des.|15|1325|doi:10.1021/cg5017388
CCDC 1418715: Experimental Crystal Structure Determination
Related Article: Willian X.C. Oliveira, Cynthia L.M. Pereira, Carlos B. Pinheiro, Klaus Krambrock, Thais Grancha, Nícolas Moliner, Francesc Lloret, Miguel Julve|2016|Polyhedron|117|710|doi:10.1016/j.poly.2016.07.014
CCDC 909392: Experimental Crystal Structure Determination
Related Article: Tatiana R.G. Simoes, Raquel V. Mambrini, Daniella O. Reis,Maria V. Marinho, Marcos A. Ribeiro, Carlos B. Pinheiro, Jesus Ferrando-Soria, Mariadel Deniz, Catalina Ruiz-Perez, Danielle Cangussu,Humberto O. Stumpf, Francesc Lloret, Miguel Julve|2013|Dalton Trans.|42|5778|doi:10.1039/C3DT32949F
CCDC 1469225: Experimental Crystal Structure Determination
Related Article: Willian X. C. Oliveira, Carlos B. Pinheiro, Marinez M. da Costa, Ana P. S. Fontes, Wallace C. Nunes, Francesc Lloret, Miguel Julve, Cynthia L. M. Pereira|2016|Cryst.Growth Des.|16|4094|doi:10.1021/acs.cgd.6b00613
CCDC 909388: Experimental Crystal Structure Determination
Related Article: Tatiana R.G. Simoes, Raquel V. Mambrini, Daniella O. Reis,Maria V. Marinho, Marcos A. Ribeiro, Carlos B. Pinheiro, Jesus Ferrando-Soria, Mariadel Deniz, Catalina Ruiz-Perez, Danielle Cangussu,Humberto O. Stumpf, Francesc Lloret, Miguel Julve|2013|Dalton Trans.|42|5778|doi:10.1039/C3DT32949F
CCDC 1843195: Experimental Crystal Structure Determination
Related Article: Willian X. C. Oliveira, Walace D. do Pim, Carlos B. Pinheiro, Yves Journaux, Miguel Julve, Cynthia L. M. Pereira|2019|CrystEngComm|21|2818|doi:10.1039/C9CE00215D
CCDC 1843197: Experimental Crystal Structure Determination
Related Article: Willian X. C. Oliveira, Walace D. do Pim, Carlos B. Pinheiro, Yves Journaux, Miguel Julve, Cynthia L. M. Pereira|2019|CrystEngComm|21|2818|doi:10.1039/C9CE00215D
CCDC 923163: Experimental Crystal Structure Determination
Related Article: Maria V. Marinho, Tatiana R. G. Simões, Marcos A. Ribeiro, Cynthia L. M. Pereira, Flávia C. Machado, Carlos B. Pinheiro, Humberto O. Stumpf, Joan Cano, Francesc Lloret, and Miguel Julve|2013|Inorg.Chem.|52|8812|doi:10.1021/ic401038c
CCDC 1031230: Experimental Crystal Structure Determination
Related Article: Walace D. do Pim, Érica N. de Faria, Willian X. C. Oliveira, Carlos B. Pinheiro, Wallace C. Nunes, Joan Cano, Francesc Lloret, Miguel Julve, Humberto O. Stumpf, Cynthia L. M. Pereira|2015|Dalton Trans.|44|10939|doi:10.1039/C5DT00996K
CCDC 1402554: Experimental Crystal Structure Determination
Related Article: Willian X. C. Oliveira, Cynthia L. M. Pereira, Carlos B. Pinheiro, Joan Cano, Francesc Lloret, Miguel Julve|2015|Chem.Commun.|51|11806|doi:10.1039/C5CC04285B
CCDC 942308: Experimental Crystal Structure Determination
Related Article: Tatiana R. G. Simões, Walace D. do Pim, Ingrid F. Silva, Willian X. C. Oliveira, Carlos B. Pinheiro, Cynthia L. M. Pereira, Francesc Lloret, Miguel Julve, Humberto O. Stumpf|2013|CrystEngComm|15|10165|doi:10.1039/C3CE41783B
CCDC 1402553: Experimental Crystal Structure Determination
Related Article: Willian X. C. Oliveira, Cynthia L. M. Pereira, Carlos B. Pinheiro, Joan Cano, Francesc Lloret, Miguel Julve|2015|Chem.Commun.|51|11806|doi:10.1039/C5CC04285B
CCDC 1469223: Experimental Crystal Structure Determination
Related Article: Willian X. C. Oliveira, Carlos B. Pinheiro, Marinez M. da Costa, Ana P. S. Fontes, Wallace C. Nunes, Francesc Lloret, Miguel Julve, Cynthia L. M. Pereira|2016|Cryst.Growth Des.|16|4094|doi:10.1021/acs.cgd.6b00613
CCDC 1454962: Experimental Crystal Structure Determination
Related Article: Willian X.C. Oliveira, Cynthia L.M. Pereira, Carlos B. Pinheiro, Klaus Krambrock, Thais Grancha, Nícolas Moliner, Francesc Lloret, Miguel Julve|2016|Polyhedron|117|710|doi:10.1016/j.poly.2016.07.014
CCDC 1469222: Experimental Crystal Structure Determination
Related Article: Willian X. C. Oliveira, Carlos B. Pinheiro, Marinez M. da Costa, Ana P. S. Fontes, Wallace C. Nunes, Francesc Lloret, Miguel Julve, Cynthia L. M. Pereira|2016|Cryst.Growth Des.|16|4094|doi:10.1021/acs.cgd.6b00613
CCDC 1818144: Experimental Crystal Structure Determination
Related Article: Willian X. C. Oliveira, Cynthia L. M. Pereira, Carlos B. Pinheiro, Francesc Lloret, Miguel Julve|2018|Inorg.Chem.Front.|5|1294|doi:10.1039/c8qi00191j
CCDC 927505: Experimental Crystal Structure Determination
Related Article: Walace D. do Pim, Willian X. C. Oliveira, Marcos A. Ribeiro, Érica N. de Faria, Ivo F. Teixeira, Humberto O. Stumpf, Rochel M. Lago, Cynthia L. M. Pereira, Carlos B. Pinheiro, João C. D. Figueiredo-Júnior, Wallace C. Nunes, Patterson P. de Souza, Emerson F. Pedroso, María Castellano, Joan Cano, Miguel Julve|2013|Chem.Commun.|49|10778|doi:10.1039/C3CC46242K
CCDC 1818143: Experimental Crystal Structure Determination
Related Article: Willian X. C. Oliveira, Cynthia L. M. Pereira, Carlos B. Pinheiro, Francesc Lloret, Miguel Julve|2018|Inorg.Chem.Front.|5|1294|doi:10.1039/c8qi00191j
CCDC 1034455: Experimental Crystal Structure Determination
Related Article: Willian X. C. Oliveira, Marcos A. Ribeiro, Carlos B. Pinheiro, Marinez M. da Costa, Ana Paula S. Fontes, Wallace C. Nunes, Danielle Cangussu, Miguel Julve, Humberto O. Stumpf, Cynthia L. M. Pereira|2015|Cryst.Growth Des.|15|1325|doi:10.1021/cg5017388
CCDC 1409933: Experimental Crystal Structure Determination
Related Article: Nathália R. de Campos, Marcos A. Ribeiro, Willian X. C. Oliveira, Daniella O. Reis, Humberto O. Stumpf, Antônio C. Doriguetto, Flávia C. Machado, Carlos B. Pinheiro, Francesc Lloret, Miguel Julve, Joan Cano, Maria V. Marinho|2016|Dalton Trans.|45|172|doi:10.1039/C5DT03401A
CCDC 927507: Experimental Crystal Structure Determination
Related Article: Walace D. do Pim, Willian X. C. Oliveira, Marcos A. Ribeiro, Érica N. de Faria, Ivo F. Teixeira, Humberto O. Stumpf, Rochel M. Lago, Cynthia L. M. Pereira, Carlos B. Pinheiro, João C. D. Figueiredo-Júnior, Wallace C. Nunes, Patterson P. de Souza, Emerson F. Pedroso, María Castellano, Joan Cano, Miguel Julve|2013|Chem.Commun.|49|10778|doi:10.1039/C3CC46242K
CCDC 1409935: Experimental Crystal Structure Determination
Related Article: Nathália R. de Campos, Marcos A. Ribeiro, Willian X. C. Oliveira, Daniella O. Reis, Humberto O. Stumpf, Antônio C. Doriguetto, Flávia C. Machado, Carlos B. Pinheiro, Francesc Lloret, Miguel Julve, Joan Cano, Maria V. Marinho|2016|Dalton Trans.|45|172|doi:10.1039/C5DT03401A
CCDC 942307: Experimental Crystal Structure Determination
Related Article: Tatiana R. G. Simões, Walace D. do Pim, Ingrid F. Silva, Willian X. C. Oliveira, Carlos B. Pinheiro, Cynthia L. M. Pereira, Francesc Lloret, Miguel Julve, Humberto O. Stumpf|2013|CrystEngComm|15|10165|doi:10.1039/C3CE41783B
CCDC 1034458: Experimental Crystal Structure Determination
Related Article: Willian X. C. Oliveira, Marcos A. Ribeiro, Carlos B. Pinheiro, Marinez M. da Costa, Ana Paula S. Fontes, Wallace C. Nunes, Danielle Cangussu, Miguel Julve, Humberto O. Stumpf, Cynthia L. M. Pereira|2015|Cryst.Growth Des.|15|1325|doi:10.1021/cg5017388
CCDC 909389: Experimental Crystal Structure Determination
Related Article: Tatiana R.G. Simoes, Raquel V. Mambrini, Daniella O. Reis,Maria V. Marinho, Marcos A. Ribeiro, Carlos B. Pinheiro, Jesus Ferrando-Soria, Mariadel Deniz, Catalina Ruiz-Perez, Danielle Cangussu,Humberto O. Stumpf, Francesc Lloret, Miguel Julve|2013|Dalton Trans.|42|5778|doi:10.1039/C3DT32949F
CCDC 1031229: Experimental Crystal Structure Determination
Related Article: Walace D. do Pim, Ingrid F. Silva, Eufrânio N. da Silva Júnior, Humberto O. Stumpf, Willian X. C. Oliveira, Emerson F. Pedroso, Carlos B. Pinheiro, Yves Journaux, Felipe Fantuzzi, Ivo Krummenacher, Holger Braunschweig, Bernd Engels, Joan Cano, Miguel Julve, Cynthia L. M. Pereira|2021|Dalton Trans.|50|12430|doi:10.1039/D1DT02268G
CCDC 927506: Experimental Crystal Structure Determination
Related Article: Walace D. do Pim, Willian X. C. Oliveira, Marcos A. Ribeiro, Érica N. de Faria, Ivo F. Teixeira, Humberto O. Stumpf, Rochel M. Lago, Cynthia L. M. Pereira, Carlos B. Pinheiro, João C. D. Figueiredo-Júnior, Wallace C. Nunes, Patterson P. de Souza, Emerson F. Pedroso, María Castellano, Joan Cano, Miguel Julve|2013|Chem.Commun.|49|10778|doi:10.1039/C3CC46242K
CCDC 1469226: Experimental Crystal Structure Determination
Related Article: Willian X. C. Oliveira, Carlos B. Pinheiro, Marinez M. da Costa, Ana P. S. Fontes, Wallace C. Nunes, Francesc Lloret, Miguel Julve, Cynthia L. M. Pereira|2016|Cryst.Growth Des.|16|4094|doi:10.1021/acs.cgd.6b00613
CCDC 909390: Experimental Crystal Structure Determination
Related Article: Tatiana R.G. Simoes, Raquel V. Mambrini, Daniella O. Reis,Maria V. Marinho, Marcos A. Ribeiro, Carlos B. Pinheiro, Jesus Ferrando-Soria, Mariadel Deniz, Catalina Ruiz-Perez, Danielle Cangussu,Humberto O. Stumpf, Francesc Lloret, Miguel Julve|2013|Dalton Trans.|42|5778|doi:10.1039/C3DT32949F
CCDC 1409934: Experimental Crystal Structure Determination
Related Article: Nathália R. de Campos, Marcos A. Ribeiro, Willian X. C. Oliveira, Daniella O. Reis, Humberto O. Stumpf, Antônio C. Doriguetto, Flávia C. Machado, Carlos B. Pinheiro, Francesc Lloret, Miguel Julve, Joan Cano, Maria V. Marinho|2016|Dalton Trans.|45|172|doi:10.1039/C5DT03401A
CCDC 1553972: Experimental Crystal Structure Determination
Related Article: Willian X. C. Oliveira, Cynthia L.M. Pereira, Carlos B. Pinheiro, Francesc Lloret, Miguel Julve|2018|J.Coord.Chem.|71|707|doi:10.1080/00958972.2018.1428313
CCDC 1409932: Experimental Crystal Structure Determination
Related Article: Nathália R. de Campos, Marcos A. Ribeiro, Willian X. C. Oliveira, Daniella O. Reis, Humberto O. Stumpf, Antônio C. Doriguetto, Flávia C. Machado, Carlos B. Pinheiro, Francesc Lloret, Miguel Julve, Joan Cano, Maria V. Marinho|2016|Dalton Trans.|45|172|doi:10.1039/C5DT03401A
CCDC 1558468: Experimental Crystal Structure Determination
Related Article: Natalia V. Reis, Wdeson P. Barros, Willian X. C. Oliveira, Cynthia L. M. Pereira, Willian R. Rocha, Carlos B. Pinheiro, Francesc Lloret, Miguel Julve, Humberto O. Stumpf|2018|Eur.J.Inorg.Chem.||477|doi:10.1002/ejic.201700821
CCDC 909391: Experimental Crystal Structure Determination
Related Article: Tatiana R.G. Simoes, Raquel V. Mambrini, Daniella O. Reis,Maria V. Marinho, Marcos A. Ribeiro, Carlos B. Pinheiro, Jesus Ferrando-Soria, Mariadel Deniz, Catalina Ruiz-Perez, Danielle Cangussu,Humberto O. Stumpf, Francesc Lloret, Miguel Julve|2013|Dalton Trans.|42|5778|doi:10.1039/C3DT32949F
CCDC 1553973: Experimental Crystal Structure Determination
Related Article: Willian X. C. Oliveira, Cynthia L.M. Pereira, Carlos B. Pinheiro, Francesc Lloret, Miguel Julve|2018|J.Coord.Chem.|71|707|doi:10.1080/00958972.2018.1428313
CCDC 1843194: Experimental Crystal Structure Determination
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CCDC 1843196: Experimental Crystal Structure Determination
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