6533b7dcfe1ef96bd1271f8b
RESEARCH PRODUCT
Relatively strong intramolecular antiferromagnetic coupling in a neutral Cr(III)2Nb(V)2 heterobimetallic molecular square.
Miguel JulveCarlos B. PinheiroWillian X. C. OliveiraFrancesc LloretCynthia L. M. PereiraJoan Canosubject
ChemistryMetals and Alloyschemistry.chemical_elementGeneral ChemistryType (model theory)CatalysisAntiferromagnetic couplingSquare (algebra)Surfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsIonCrystallographyChromiumComputational chemistryIntramolecular forceMaterials ChemistryCeramics and CompositesDiamagnetismAntiferromagnetismdescription
A relatively large antiferromagnetic interaction between the two chromium(III) ions from the molecular square [{Cr(dmso)4}2{Nb(μ-O)2(C2O4)2}2] () (J = -12.0 cm(-1)) is mediated by the diamagnetic oxo-Nb(V)-oxo pathway, its nature and magnitude being substantiated by DFT type theoretical calculations.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2015-06-26 | Chemical communications (Cambridge, England) |