Unexpected formation of a dodecanuclear {CoII6CuII6} nanowheel under ambient conditions: magneto-structural correlations.

6533b859fe1ef96bd12b6eb3

RESEARCH PRODUCT

Unexpected formation of a dodecanuclear {CoII6CuII6} nanowheel under ambient conditions: magneto-structural correlations.

Ingrid F. Silva Yves Journaux Bernd Engels Willian X. C. Oliveira Walace D. Do Pim Walace D. Do Pim Carlos B. Pinheiro Emerson F. Pedroso Humberto O. Stumpf Miguel Julve Ivo Krummenacher Cynthia L. M. Pereira Felipe Fantuzzi Holger Braunschweig Joan Cano Eufrânio N. Da Silva Júnior

subject

Inorganic Chemistry Materials science Future studies Chemical physics Isotropy Anisotropy Magneto Environmentally friendly Hamiltonian (control theory)Metal clusters

description

We report the unique heterobimetallic dodecanuclear oxamate-based {CoII6CuII6} nanowheel obtained using an environmentally friendly synthetic protocol. The effective Hamiltonian methodology employed herein allows the rationalisation of magnetic isotropic or anisotropic metal clusters, being a significant advance for future studies of exciting properties only observed at low and ultralow temperatures.

year	journal	country	edition	language
2021-09-21	Dalton transactions (Cambridge, England : 2003)

10.1039/d1dt02268g https://pubmed.ncbi.nlm.nih.gov/34545875

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