0000000001314377

AUTHOR

Matthias Hardy

showing 3 related works from this author

Stepwise Construction of Heterobimetallic Cages by an Extended Molecular Library Approach.

2017

Two novel heterobimetallic complexes, a trigonal-bipyramidal and a cubic one, have been synthesized and characterized using the same C3-symmetric metalloligand, prepared by a simple subcomponent self-assembly strategy. Adopting the molecular library approach, we chose a mononuclear, preorganized iron(II) complex as the metalloligand capable of self-assembly into a trigonal-bipyramidal or a cubic aggregate upon coordination to cis-protected C2-symmetric palladium(II) or unprotected tetravalent palladium(II) ions, respectively. The trigonal-bipyramidal complex was characterized by NMR and UV–vis spectroscopy, electrospray ionization mass spectrometry (ESI-MS), and single-crystal X-ray diffrac…

010405 organic chemistryChemistrytrigonal-bipyramidal and cubic heterobimetallic cagesElectrospray ionizationchemistry.chemical_element010402 general chemistry01 natural sciencesCombinatorial chemistry0104 chemical sciencesIonInorganic ChemistryCrystallographyPhysical and Theoretical ChemistrySpectroscopyta116extended molecular library approachPalladiumInorganic chemistry
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CCDC 1550913: Experimental Crystal Structure Determination

2017

Related Article: Matthias Hardy, Niklas Struch, Filip Topic, Gregor Schnakenburg, Kari Rissanen, Arne Lützen|2018|Inorg.Chem.|57|3507|doi:10.1021/acs.inorgchem.7b02516

Space GroupCrystallographyCrystal SystemCrystal Structure(NNN-tris(2-((((34'-bipyridin)-6-yl)methylidene)amino)ethyl)amine)-iron bis(tetrafluoroborate)Cell ParametersExperimental 3D Coordinates
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CCDC 1575238: Experimental Crystal Structure Determination

2017

Related Article: Matthias Hardy, Niklas Struch, Filip Topic, Gregor Schnakenburg, Kari Rissanen, Arne Lützen|2018|Inorg.Chem.|57|3507|doi:10.1021/acs.inorgchem.7b02516

bis(mu-NNN-tris(2-((((34'-bipyridin)-6-yl)methylidene)amino)ethyl)amine)-tris((propane-13-diyl)bis(diphenylphosphine))-di-iron-tri-palladium tetrafluoroborate trifluoromethanesulfonate acetonitrile solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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