Author: N. Ovèjak

0000000001316536

AUTHOR

N. Ovèjak

Novel Hexanuclear Copper(II) Complex Built from a Simple Tetrachelating Triazole Ligand: Synthesis, Structure, and Magnetism

A new easy symmetric 3,5-disubstituted 1,2,4-triazole ligand (H3diV) by reaction with an excess of copper(II) salt has afforded a novel hexanuclear compound (Cu/HdiV ratio of 6:2) through a bis(trans-cis-cis-trans) binding mode, exhibiting two types of Cu(II) centers and two clearly distinguishable antiferromagnetic J1 (-234 cm(-1)) and J2 (-35 cm(-1)) coupling constants.

research product

CCDC 918812: Experimental Crystal Structure Determination

Related Article: J. Hernández-Gil, N. Ovèjak, S. Ferrer, F. Lloret, and A. Castiñeiras|2013|Inorg.Chem.|52|2289|doi:10.1021/ic3027946

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