Author: Miao Du

0000000001317581

AUTHOR

Miao Du

Ferromagnetic coupling in a one-dimensional molecular railroad copper(II) azido compound containing a defective double cubane motif.

The compound [Cu2(bpm)2(N3)4]n (bpm = bis(pyrazol-1−yl)methane) shows three unique coordination modes (μ1,1-, μ1,1,1-, μ1,1,3-N3) and ferromagnetic interaction between the copper(II) ions. The structure of the compound exhibits a one-dimensional railroad polymer made up of repeating defective dicubane-type units linked by μ1,1,3-N3 bridges.

research product

CCDC 143382: Experimental Crystal Structure Determination

Related Article: Lei Zhang, Liang-Fu Tang, Zhi-Hong Wang, Miao Du, Miguel Julve, F.Lloret, Ji-Tao Wang|2001|Inorg.Chem.|40|3619|doi:10.1021/ic001406f

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