0000000001319229
AUTHOR
Eko Adi Prasetyanto
Selective Encapsulation and Enhancement of the Emission Properties of a Luminescent Cu(I) Complex in Mesoporous Silica
Selective encapsulation and enhancement of the emission properties of a luminescent Cu(I) complex in mesoporous silica
We describe a synthetic approach to prepare new luminescent silica‐based materials through the encapsulation of a neutral copper(I) complex inside the pores of mesoporous silica nanoparticles (MSN). The copper(I) complex is present, in the solid state, as two polymorphs, blue and yellow emissive, and in solution it shows a pale yellow color that is also mirrored by an emission in the yellow‐orange region of the electromagnetic spectrum. The X‐ray structures of single crystals have been obtained for both polymorphs. The complex encapsulation in MSN is achieved by its entrapment inside micelles followed by condensation of the silica source. Interestingly, the entrapment leads to the isolation…
CCDC 1481069: Experimental Crystal Structure Determination
Related Article: Loïc Donato, Celine Rosticher, Eko Adi Prasetyanto, Pengkun Chen, Claudia Bizzarri, Kari Rissanen, Luisa De Cola|2018|Helv.Chim.Acta|101|e1700273|doi:10.1002/hlca.201700273
CCDC 1481420: Experimental Crystal Structure Determination
Related Article: Loïc Donato, Celine Rosticher, Eko Adi Prasetyanto, Pengkun Chen, Claudia Bizzarri, Kari Rissanen, Luisa De Cola|2018|Helv.Chim.Acta|101|e1700273|doi:10.1002/hlca.201700273