0000000001320113
AUTHOR
Caihong Luo
Electrosynthesis as a powerful method for the generation of catalytic intermediates: efficient isolation of a palladium aryl halide oxidative addition product.
International audience; Polyphosphane ligands of controlled conformation promote highly efficient palladium-catalyzed cross-coupling reactions. Electrosynthesis has been used as a new straightforward method to obtain important intermediates in the search for a better mechanistic understanding. As a proof of concept, the facile synthesis of a phenyl iodopalladium(II) complex (2) was conducted at the electrolysis scale from a readily electrogenerated unstable Pd0 precursor.
CCDC 814626: Experimental Crystal Structure Determination
Related Article: V.A.Zinovyeva, Caihong Luo, S.Fournier, C.H.Devillers, H.Cattey, H.Doucet, J.-C.Hierso, D.Lucas|2011|Chem.-Eur.J.|17|9901|doi:10.1002/chem.201100629