0000000001320238
AUTHOR
Guoqi Zhang
Not just size and shape: spherically symmetrical d5 and d10 metal ions give different coordination nets with 4,2′:6′,4″-terpyridines
Functionalized 4,2′:6′,4″-terpyridine ligands have been used to provide a divergent N,N′-donor set for the formation of coordination polymers containing {Zn2(µ-OAc)4} or {Mn3(µ-OAc)4(OAc)2} scaffolds. Single-stranded coordination polymers are produced from the reactions of 4′-(4-bromophenyl)-4,2′:6′,4″-terpyridine (1) and 4′-(4-methylthiophenyl)-4,2′:6′,4″-terpyridine (2) with Zn(OAc)2·2H2O. In [Zn2(1)(OAc)4]n and [Zn2(2)(OAc)4]n, the two outer nitrogen donors of the 4,2′:6′,4″-terpyridine ligands, bind to the axial sites of {Zn2(µ-OAc)4} units to generate coordination polymer chains which are π-stacked so that the V-shaped ligand domains are interleaved. When Mn(OAc)2·4H2O is treated with …
CCDC 758781: Experimental Crystal Structure Determination
Related Article: E.C.Constable, Guoqi Zhang, E.Coronado, C.E.Housecroft, M.Neuburger|2010|CrystEngComm|12|2139|doi:10.1039/b926597j
CCDC 758780: Experimental Crystal Structure Determination
Related Article: E.C.Constable, Guoqi Zhang, E.Coronado, C.E.Housecroft, M.Neuburger|2010|CrystEngComm|12|2139|doi:10.1039/b926597j
CCDC 758782: Experimental Crystal Structure Determination
Related Article: E.C.Constable, Guoqi Zhang, E.Coronado, C.E.Housecroft, M.Neuburger|2010|CrystEngComm|12|2139|doi:10.1039/b926597j