0000000001320238

AUTHOR

Guoqi Zhang

showing 4 related works from this author

Not just size and shape: spherically symmetrical d5 and d10 metal ions give different coordination nets with 4,2′:6′,4″-terpyridines

2010

Functionalized 4,2′:6′,4″-terpyridine ligands have been used to provide a divergent N,N′-donor set for the formation of coordination polymers containing {Zn2(µ-OAc)4} or {Mn3(µ-OAc)4(OAc)2} scaffolds. Single-stranded coordination polymers are produced from the reactions of 4′-(4-bromophenyl)-4,2′:6′,4″-terpyridine (1) and 4′-(4-methylthiophenyl)-4,2′:6′,4″-terpyridine (2) with Zn(OAc)2·2H2O. In [Zn2(1)(OAc)4]n and [Zn2(2)(OAc)4]n, the two outer nitrogen donors of the 4,2′:6′,4″-terpyridine ligands, bind to the axial sites of {Zn2(µ-OAc)4} units to generate coordination polymer chains which are π-stacked so that the V-shaped ligand domains are interleaved. When Mn(OAc)2·4H2O is treated with …

chemistry.chemical_classificationCoordination polymerLigandMetal ions in aqueous solutionGeneral ChemistryPolymerCondensed Matter PhysicsIonchemistry.chemical_compoundCrystallographychemistryPyridineAntiferromagnetismGeneral Materials ScienceGround stateCrystEngComm
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CCDC 758781: Experimental Crystal Structure Determination

2011

Related Article: E.C.Constable, Guoqi Zhang, E.Coronado, C.E.Housecroft, M.Neuburger|2010|CrystEngComm|12|2139|doi:10.1039/b926597j

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-((mu~2~-4'-(4-Bromophenyl)-42':6'4''-terpyridine)-tetrakis(acetato)-di-zinc(ii))Experimental 3D Coordinates
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CCDC 758780: Experimental Crystal Structure Determination

2011

Related Article: E.C.Constable, Guoqi Zhang, E.Coronado, C.E.Housecroft, M.Neuburger|2010|CrystEngComm|12|2139|doi:10.1039/b926597j

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-(hexakis(mu~2~-4'-(4-Bromophenyl)-42':6'4''-terpyridine)-octakis(mu~2~-acetato)-tetraacetato-hexa-manganese methanol solvate hydrate)Cell ParametersExperimental 3D Coordinates
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CCDC 758782: Experimental Crystal Structure Determination

2011

Related Article: E.C.Constable, Guoqi Zhang, E.Coronado, C.E.Housecroft, M.Neuburger|2010|CrystEngComm|12|2139|doi:10.1039/b926597j

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-((mu~2~-4'-(4-methylthiophenyl)-42':6'4''-terpyridine)-tetrakis(acetato)-di-zinc(ii))Cell ParametersExperimental 3D Coordinates
researchProduct