0000000001320822
AUTHOR
D. Kalavathy
Tetra-μ-chlorido-bis(18-crown-6)platinum(II)dipotassium(I)
In the title compound, [K(2)PtCl(4)(C(12)H(24)O(6))(2)], the Pt(II) ion is located on an inversion centre and is coordinated by four Cl atoms, forming a square-planar geometry. The K(I) ion is coordinated by six O atoms of the crown ether and two bridging Cl atoms. The K(I) ion is displaced by 0.756 (2) Å from the mean plane of the six O atoms of the crown ether. The mol-ecules are connected by weak C-H⋯O hydrogen bonds, forming an infinite two-dimensional network parallel to the (10) plane. Intra- and inter-molecular C-H⋯Cl hydrogen bonds are also observed.
CCDC 781217: Experimental Crystal Structure Determination
Related Article: B.R.D.Nayagam, S.R.Jebas, D.Kalavathy, R.Murugesan, D.Schollmeyer|2010|Acta Crystallogr.,Sect.E:Struct.Rep.Online|66|m667|doi:10.1107/S1600536810016648