Author: Rosely A. Peralta

0000000001323107

AUTHOR

Rosely A. Peralta

Luminescent PhotoCORMs: Enabling/Disabling CO Delivery upon Blue Light Irradiation.

The new luminescent carbonyl compounds [Mn(Oxa-H)(CO)3Br] (1) and [Mn(Oxa-NMe2)(CO)3Br] (2) were synthesized and fully characterized. Complexes 1 and 2 showed CO release under blue light (λ453). Spectroscopic techniques and TD-DFT and SOC-TD-DFT calculations indicated that 1 and 2 release the Oxa-H and Oxa-NMe2 coligands in addition to the carbonyl ligands, increasing the luminescence during photoinduction.

research product

CCDC 1982518: Experimental Crystal Structure Determination

Related Article: Vitor C. Weiss, Giliandro Farias, André L. Amorim, Fernando R. Xavier, Tiago P. Camargo, Mayana B. Bregalda, Matti Haukka, Ebbe Nordlander, Bernardo de Souza, Rosely A. Peralta|2020|Inorg.Chem.|59|13078|doi:10.1021/acs.inorgchem.0c00638

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PEPhysical Sciences and Engineering
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LSLife Sciences
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