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RESEARCH PRODUCT
Tetraiodoethynyl resorcinarene cavitands as multivalent halogen bond donors
Kari RissanenArto ValkonenArto ValkonenLotta TurunenNgong Kodiah BeyehFangfang Pansubject
inorganic chemicalsHalogen bondChemistryMetals and Alloyschemistry.chemical_elementGeneral ChemistryResorcinarenePhotochemistryOxygenNitrogenCatalysis3. Good healthSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry.chemical_compoundBromidePolymer chemistryHalogenMaterials ChemistryCeramics and Compositesta116description
The first examples of iodoethynyl resorcinarene cavitands as rigid 3D halogen bond (XB) donor molecules are presented. These concave macrocycles form strong, RXB = 0.78–0.83, halogen bonds with dioxane oxygen, pyridine nitrogen and a bromide anion in tetraproropyl ammonium bromide resulting in deep cavity cavitand structures.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2014-11-08 | Chemical communications |